Answer:
Products are favored.
Explanation:
The acid-base reaction of CH₃COOH (acid) with NH₃ (base) produce:
CH₃COOH + NH₃ ⇄ CH₃COO⁻ + NH₄⁺ Kr = ?
It is possible to know Kr of the reaction by the sum of acidic dissociations of the half-reactions. That is:
CH₃COOH ⇄ CH₃COO⁻ + H⁺ Ka = 1.8x10⁻⁵
NH₃ + H⁺ ⇄ NH₄⁺ 1/Ka = 1/ 5.6x10⁻¹⁰ = 1.8x10⁹
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CH₃COOH + NH₃ ⇄ CH₃COO⁻ + NH₄⁺ Kr = 1.8x10⁻⁵×1.8x10⁹ = <em>3.2x10⁴</em>
<em> </em>
As Kr is defined as:
Kr = [CH₃COO⁻] [NH₄⁺] / [CH₃COOH] [NH₃]
And Kr is > 1
[CH₃COO⁻] [NH₄⁺] > [CH₃COOH] [NH₃],
showing <em>products are favored</em>.
Explanation:
Contributing structures are the resonating structures which are formed due to the delocalization of electrons in a molecule.
The azide ion that is
, is a symmetrical ion, all of whose contributing structures have formal charges.
Lone pair of central nitrogen atom in azide ion is in conjugation with the neighboring nitrogen atoms.
Contributing structures of azide ion are drawn in the image attached.
Answer:
100g / (5.2g/cm3)
= 100g / (5.2g / 1cm3)
= 100g x 1cm3 / 5.2 g
= 19.2 cm3
Since 1 cm3 = 1 ml, your answer is 19.2 ml.