ΔG⁰ = ΔH⁰ - TΔS
ΔH⁰ = Hf,(CH₃OH) - Hf,(CO) = -238.7 + 110.5 = -128.2 kJ/mol
ΔS = S(CH₃OH) - S(CO) - 2S(H₂) = 126.8 - 197.7 - 2 x 130.6 = -332.1 J/mol.K
So
ΔG⁰ = - 128200 + 332.1 T
For the reaction to be spontaneous:
ΔG⁰ < 0
So: -128200 + 332.1 T < 0
332.1 T < 128200
T < 386.028 K
D has a total of four significant figures.
there are 6 moles of oxygen in Zn(No3)2
<span>70.4 mg CO2 x 1.0 g /1000 mg x 1 mole CO2/ 44 gCO2 x 1 mole C/1 mole CO2 = 0.0016 moles C
14.4 mg H2O x 1.0 g/1000 mg x 1 mole H2O/18 g H2O x 2 moles H/ 1 mole H2O = 0.0016 moles O
molar mass of C=12 g/mole
molar mass of H=1 g/mole
0.0016 moles C x 12 g C/ 1 mole C = 0.0192 g C or 19.2 mg C
0.00156 moles H x 1 g H/1 mole H = 0.00156 g H or 1.56 mg H
mg O= 30.4 mg vanillin - 19.2 mg C – 1.56 mg H = 9.64 mg O
molar mass of O=16 g/mole
9.64 mg O x 1 g/1000 mg x 1 mole O/16.0 g = 0.000602
C.0016 H.0016 O.000602; divide all the moles by the smallest value of0.000602
C2.66H2.66O1 is the empirical formula;
to obtain whole numbers multiply by 3
3[C2.66H2.66O1] = C8H8O3
above formula weight: 8(C) + 8(H) + 3(O) = 8(12) + 8(1) + 3(16) = 152 amu
The empirical formula weight and the molecular formula weight are the same .
Molecular formula is C8H8O3.</span>
1.question, 2.observe, 3.hypothesize, 4.experiment 5.conclusion, 6. record.
