Answer is: H₂O → H⁺ + OH⁻.
Water dissociates (autoionization) to form hydrogen ions (H⁺) and hydroxide (OH⁻) ions. The protons (H⁺) hydrate as hydroxonium ions( H₃O⁺).
The Kw (the ionic product for water) at 25°C is 1·10⁻¹⁴ mol²/dm⁶ or 1·10⁻¹⁴ M². Concentration of hydrogen ions and hydroxide ions in pure water are the same.
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Answer: It decreases because nonvolatile aluminum and chloride ions now occupy some of the volume of the system.
Explanation:
Vapor pressure of a liquid is defined as the pressure exerted by the vapors in equilibrium with the liquid/solution at a particular temperature.
So, when a non-volatile solute is added to a solvent then its molecules align at the surface of liquid. As a result, less number of solvent molecules will escape from the solution. Thus, there will be decrease in vapors and thus the vapor pressure decrease.
The relative lowering of vapor pressure is directly proportional to the amount of dissolved solute.
Data:
V1 = 6.7 liter
T1 = 23° = 23 + 273.15 K = 300.15 K
P1 = 0.98 atm
V2 = 2.7 liter
T2 = 125° = 125 + 273.15 K = 398.15 K
P2 = ?
Formula:
Combined law of ideal gases: P1 V1 / T1 = P2 V2 / T2
=> P2 = P1 V1 T2 / (T1 V2)
P2 = 0.98 atm * 6.7 liter * 398.15 K / (300.15K * 2.7 liter)
P2 = 3.22 atm