First we will calculate free energy change:
ΔG₀ = ΔH₀ - (T * ΔS₀)
= - 793 kJ - (298 * - 0.319 kJ/K) = - 698 kJ
We know the relation between free energy change and cell potential is:
ΔG₀ = - n F E⁰ where
F = Faraday's constant = 96485 C/mol
n = 2 (given by equation that the electrons involved is 2)
ΔG₀ = - 2 x 96485 x E⁰
- 698 kJ = - 2 x 96485 x E⁰
E⁰ = (698 x 1000) / (2 x 96485) = 3.62 volts
Explanation:
the lone pairs will be negatively charged. these have a repulsion effect on other negatively charged electrons in the shells of atoms. picture a water molecule: the lone electron pair on the top of the oxygen will have a repulsion force on the 2 hydrogen atom's orbiting electrons to cause a bent molecular geometry.
The volume of your 0.25 m stock solution that is needed to make 200 ml of 0.010 m NaCl is <u>0.008 L</u>
Concentration is the abundance of a constituent divided by way of the overall volume of an aggregate. several sorts of mathematical descriptions may be outstanding: mass concentration, molar concentration, variety concentration, and extent awareness.
Calculation:-
C₁ = 0.25 M
V₁ = ?
C₂ = 0.010 M
V₂ = 200 ml = 0.2 L
V₁ = C₂V₂/C₁
= 0.010 × 0.2 / 0.25
=<u> 0.008 L</u>
The concentration of a substance is the quantity of solute found in a given amount of solution. Concentrations are normally expressed in terms of molarity, defined because of the variety of moles of solute in 1 L of answer.
The Concentration of an answer is a measure of the quantity of solute that has been dissolved in a given amount of solvent or answer. A concentrated answer is one that has a rather huge quantity of dissolved solute.
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The atoms that would be expected to be diamagnetic in the ground state is magnesium
The magnetism of an atom refers to its electronic configuration. A diamagnetic atom is an atom whose electrons are all paired.
A paired electron is an electron that occurs in pairs in its orbital shell.
At their respective ground state, the electronic configuration of the given elements are as follows:
The electronic configuration of magnesium is 1s²2s²2p⁶3s². As such its a diamagnetic atom.
The electronic configuration of Potassium is 1s²2s²2p⁶3s²3p⁶4s¹. Hence, Potassium has one unpaired electron in its outermost shell.
The electronic configuration of Chlorine is 1s²2s²2p⁶3s²3p⁵. Hence, Chlorine has one unpaired electron in its outermost shell.
The electronic configuration of Cobalt is 1s²2s²2p⁶3s²3p⁶3d⁷4s². Hence, the unpaired electrons of Cobalt in its outermost shell are three.
Therefore, the atoms that are diamagnetic in the ground state is magnesium.
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