Answer: The 234.74 grams of sample should be ordered.
Explanation:
Let the gram of 114 Ag to ordered be 
The amount required for the beginning of experiment = 0.0575 g
Time requires to ship the sample = 4.2hour = 252 min(1 hr = 60 min)
Half life of the sample =
= 21 min

![\log[N]=\log[N_o]-\frac{\lambda t}{2.303}](https://tex.z-dn.net/?f=%5Clog%5BN%5D%3D%5Clog%5BN_o%5D-%5Cfrac%7B%5Clambda%20t%7D%7B2.303%7D)
![\log[0.0575 g]=\log[N_o]-\frac{0.033 min^{-1}\times 252 min}{2.303}](https://tex.z-dn.net/?f=%5Clog%5B0.0575%20g%5D%3D%5Clog%5BN_o%5D-%5Cfrac%7B0.033%20min%5E%7B-1%7D%5Ctimes%20252%20min%7D%7B2.303%7D)

The 234.74 grams of sample should be ordered.
Answer : The pH value of an acid is below 7.
Explanation :
pH : It is defined as the negative logarithm of hydrogen ion or hydronium ion concentration.
Mathematically,
![pH=-\log [H^+]](https://tex.z-dn.net/?f=pH%3D-%5Clog%20%5BH%5E%2B%5D)
When the pH less than 7 then the solution is acidic and the concentration of hydrogen ion is greater than hydroxide ion.
When the pH more than 7 then the solution is basic and the concentration of hydrogen ion is less than hydroxide ion.
When the pH is equal to 7 then the solution is neutral and the concentration of hydrogen ion is equal to the hydroxide ion.
Hence, the pH value of an acid is below 7.
Lithium i believe is the answer