Answer: 
Explanation: <u>Heats</u> <u>of</u> <u>formation</u> is the amount of heat necessary to create 1 mol of a compound from its molecular constituents. The basic conditions the substance is formed is at standard conditions: 1 atm and 25°C. Each compound has its own heat of formation per mol of compound (kJ/mol), but to an element is assigned a value of zero.
<u>Standard</u> <u>Enthalpy</u> <u>Change</u> is defined as the heat absorbed or released when a reaction takes place. It can be positive or negative, which means reaction is endothermic or exothermic, respectively.
Enthalpy change is calculated as the difference between the sum of heat formation of products and the sum of heat formation of the reactants:
For the reaction
2NH₃ + 3N₂O → 4N₂ + 3H₂O
2(-46.2) + 3(82.05) 4(0) + 3(-241.8)
![\Delta H^{0}=3(-241.8)-[ 2(-46.2)+3(82.05)]](https://tex.z-dn.net/?f=%5CDelta%20H%5E%7B0%7D%3D3%28-241.8%29-%5B%202%28-46.2%29%2B3%2882.05%29%5D)
<u>The standard enthalpy change for the reaction is </u><u> kJ</u>
Answer: a. 0.8 tons p. month.
Explanation:
Given: Total nuclear waste = 60,000 metric tons
Time take = 60 years = 12 x 60 months [ 1 year = 12 months]
= 720 months
Total nuclear power plants = 104
Now , Average waste produced by each plant = 
Hence, 0.8 tons p. month is produced by each plant.
So, option a. is correct.
Structure of <span>N-ethyl-3-methylpentanamide is shown below,</span>
Answer:
The product is cyclohexanol
Explanation:
Firstly,
A ketone undergo a borohydride reduction reaction to form an alcohol as below,
R-CO-R' ⇒ R-CO(OH)-R'
- IR Spectrum confirms that alcohol group is existed with the peak at 3400 cm⁻¹
- From 1H-NMR, the product has 10 hydrogen atoms, the MS suggest that the formula is C₅H₁₀O (M = 86). With this formula, the alcohol is monosaturated. Since, the substance already underwent reduction reaction, the only way to suggest a monosaturated compound is a cyclic alcohol. So the compound is cyclopentanol.
- Check with other spectroscopic properties,
- 3 signals of 13C NMR confirms the structure is symmetrical, δ 24.2, (-<u>C</u>H₂-CH₂-CH(CH₂-)-OH), δ 35.5 (-CH₂-<u>C</u>H₂-CH(CH₂-)-OH), δ 73.3 (-CH₂-CH₂-<u>C</u>H(CH₂-)-OH).
1.56 δ (4H, triplet) - (-C<u>H</u>₂-CH₂-CH-OH) ; triplet as coupling with 2 H,
1.78 δ (4H, multiplet) - (-CH₂-C<u>H</u>₂-CH-OH); multiplet as coupling with 2H of CH₂, 1 H of CH
3.24 δ (1H, quintet); - (-CH₂-CH₂-C<u>H</u>(CH₂-)-OH), coupling with4 H of 2 group of CH₂
3.58 δ (1H, singlet); - (-CH₂-CH₂-CH(CH₂-)-O<u>H</u>), hydrogen of alcohol group, not tend to coupling with other hydrogen
