Answer:
![[SO_2Cl_2]=0.0175M](https://tex.z-dn.net/?f=%5BSO_2Cl_2%5D%3D0.0175M)
Explanation:
Hello!
In this case, considering that the decomposition reaction of SO2Cl2 is first-order, we can write the rate law shown below:
![r=-k[SO_2Cl_2]](https://tex.z-dn.net/?f=r%3D-k%5BSO_2Cl_2%5D)
We also consider that the integrated rate law has been already reported as:
![[SO_2Cl_2]=[SO_2Cl_2]_0exp(-kt)](https://tex.z-dn.net/?f=%5BSO_2Cl_2%5D%3D%5BSO_2Cl_2%5D_0exp%28-kt%29)
Thus, by plugging in the initial concentration, rate constant and elapsed time we obtain:
![[SO_2Cl_2]=0.0225Mexp(-2.90x10^{-4}s^{-1}*865s)](https://tex.z-dn.net/?f=%5BSO_2Cl_2%5D%3D0.0225Mexp%28-2.90x10%5E%7B-4%7Ds%5E%7B-1%7D%2A865s%29)
![[SO_2Cl_2]=0.0175M](https://tex.z-dn.net/?f=%5BSO_2Cl_2%5D%3D0.0175M)
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Answer:
<em>293.99 g </em>
OR
<em>0.293 Kg</em>
Explanation:
Given data:
Lattice energy of Potassium nitrate (KNO3) = -163.8 kcal/mol
Heat of hydration of KNO3 = -155.5 kcal/mol
Heat to absorb by KNO3 = 101kJ
To find:
Mass of KNO3 to dissolve in water = ?
Solution:
Heat of solution = Hydration energy - Lattice energy
= -155.5 -(-163.8)
= 8.3 kcal/mol
We already know,
1 kcal/mol = 4.184 kJ/mole
Therefore,
= 4.184 kJ/mol x 8.3 kcal/mol
= 34.73 kJ/mol
Now, 34.73 kJ of heat is absorbed when 1 mole of KNO3 is dissolved in water.
For 101 kJ of heat would be
= 101/34.73
= 2.908 moles of KNO3
Molar mass of KNO3 = 101.1 g/mole
Mass of KNO3 = Molar mass x moles
= 101.1 g/mole x 2.908
= 293.99 g
= 0.293 kg
<em><u>293.99 g potassium nitrate has to dissolve in water to absorb 101 kJ of heat. </u></em>
Answer:
One with a few kinds is more likely to become unstable.
Explanation:
A lack of biodiversity means there is a lower chance of them having traits that enable them to adapt to a changing environment. A lack of biodiversity is usually caused by humans. It could be the result of habitat loss, invasive species, overexploitation, pollution, or climate change.
Answer: Rate law=
, order with respect to A is 1, order with respect to B is 2 and total order is 3. Rate law constant is 
Explanation: Rate law says that rate of a reaction is directly proportional to the concentration of the reactants each raised to a stoichiometric coefficient determined experimentally called as order.
![Rate=k[A]^x[B]^y](https://tex.z-dn.net/?f=Rate%3Dk%5BA%5D%5Ex%5BB%5D%5Ey)
k= rate constant
x = order with respect to A
y = order with respect to A
n = x+y = Total order
a) From trial 1:
(1)
From trial 2:
(2)
Dividing 2 by 1 :![\frac{4.8\times 10^{-2}}{1.2\times 10^{-2}}=\frac{k[0.10]^x[0.40]^y}{k[0.10]^x[0.20]^y}](https://tex.z-dn.net/?f=%5Cfrac%7B4.8%5Ctimes%2010%5E%7B-2%7D%7D%7B1.2%5Ctimes%2010%5E%7B-2%7D%7D%3D%5Cfrac%7Bk%5B0.10%5D%5Ex%5B0.40%5D%5Ey%7D%7Bk%5B0.10%5D%5Ex%5B0.20%5D%5Ey%7D)
therefore y=2.
b) From trial 2:
(3)
From trial 3:
(4)
Dividing 4 by 3:![\frac{9.6\times 10^{-2}}{4.8\times 10^{-2}}=\frac{k[0.20]^x[0.40]^y}{k[0.10]^x[0.40]^y}](https://tex.z-dn.net/?f=%5Cfrac%7B9.6%5Ctimes%2010%5E%7B-2%7D%7D%7B4.8%5Ctimes%2010%5E%7B-2%7D%7D%3D%5Cfrac%7Bk%5B0.20%5D%5Ex%5B0.40%5D%5Ey%7D%7Bk%5B0.10%5D%5Ex%5B0.40%5D%5Ey%7D)
, x=1
Thus rate law is ![Rate=k[A]^1[B]^2](https://tex.z-dn.net/?f=Rate%3Dk%5BA%5D%5E1%5BB%5D%5E2)
Thus order with respect to A is 1 , order with respect to B is 2 and total order is 1+2=3.
c) For calculating k:
Using trial 1: ![1.2\times 10^{-2}=k[0.10]^1[0.20]^2](https://tex.z-dn.net/?f=1.2%5Ctimes%2010%5E%7B-2%7D%3Dk%5B0.10%5D%5E1%5B0.20%5D%5E2)
.