Answer:
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Barium has a 2+ charge as it is in group 2 in the periodic table and so it has two electrons in its outer shell and chloride has a -1 charge on its chloride ion. So we will need two of the chloride ions as we have a 2+ charge to match the amount of charge on one barium ion- forming barium ion
BaCI2
The first molecule is a sensible molecule having complete octet of each atom such as C, H and O whereas the second molecule having hydrogen present between the aldehyde and methyl group and thus showing hydrogen is making bond with aldehyde and methyl as well which is not possible because hydrogen only having one electron in its octet due to which it can only form a single bond by sharing its valence electron.