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2 years ago

9

Calculate the theoretical yield for the bromination of both stilbenes

1 answer:

podryga [215]2 years ago

4 0

Answer:

cinnamic acid - 150 mg

cis-stilbene - 100 μL

trans- stilbene - 100 mg

pyridinium tribromide - 200-385 mg

For this data:

moles of cinnamic acid = 0.150 g/148.16 g/mol = 0.001 mols

Theoretical mass of dibromoproduct formed = 0.001 mol x 307.97 g/mol = 0.312 g

cis-stilbene (100 ul = 0.1 ml)

moles of cis-stilbene = 0.1 ml x 1.01 g/mol/180.25 g/mol = 0.00056 mols

Theoretical mass of dibromoproduct formed = 0.00056 mol x 340.05 g/mol = 0.19 g

trans-stilbene

moles of tran-stilbene = 0.1 g/180.25 g/mol = 0.00055 mols

Theoretical mass of dibromoproduct formed = 0.00055 mol x 340.05 g/mol = 0.19 g

Explanation:

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The whiye pigment TiO2 is prepared by the reaction of titanium tetrachloride, TiCl4, with water vapor in the gas phase:

omeli [17]

Answer:

$\boxed{\text{62.1 kJ}}$

Explanation:

The formula for calculating the enthalpy change of a reaction by using the enthalpies of formation of reactants and products is

$\Delta_{\text{r}}H^{\circ} = \sum \Delta_{\text{f}} H^{\circ} (\text{products}) - \sum\Delta_{\text{f}}H^{\circ} (\text{reactants})$

TiCl₄(g) + 2H₂O(g) ⟶ TiO₂(s) + 4HCl(g)

ΔH°f/kJ·mol⁻¹: -763.2 -241.828 -939.7 -92.307

$\begin{array}{rcl}\Delta_{\text{r}}H^{\circ} & = & [-939.7 + 4(-92.307)] - [-763.2 + 2(-241.828)\\& = & [-939.7 - 369.228] - [-763.2 - 483.656]\\& = & -1308.928 + 1246.856\\& = & \mathbf{-62.1}\\\end{array}\\\text{The amount of heat evolved is } \boxed{\textbf{62.1 kJ}}$

5 0

3 years ago

Explain why the 4s sublevel fills before the 3d begins to fill as electrons are added.

tamaranim1 [39]

Answer: The energy of the 4-s subshell is lower than the energy of 3-d subshell.

Explanation:

During the filling of electrons in subshells, the lower energy levels are filled before the higher energy levels. Also known as Aufbau principle.

Energy of the sublevel = (n + l)

where : n = Principal quantum number

l = Azimuthal quantum number(s=0,p=1,d=2,f=3)

Energy of 4-s subshell= (4+0) = 4

Energy of 3-d subshell=(3+2) = 5

Energy of 4-s subshell is lower than the energy of 3-d subshell, that is why 4s orbital is filled before the 3-d subshell.

4 0

3 years ago

Read 2 more answers

You are performing an experiment that uses 114Ag. 113Ag is radioactive, decays by beta-- emission and has a half-life of 21 minu

maxonik [38]

Answer: The 234.74 grams of sample should be ordered.

Explanation:

Let the gram of 114 Ag to ordered be $N_o$

The amount required for the beginning of experiment = 0.0575 g

Time requires to ship the sample = 4.2hour = 252 min(1 hr = 60 min)

Half life of the sample = ${t_{\frac{1}{2}}$ = 21 min

$\lambda =\frac{0.693}{t_{\frac{1}{2}}}=\frac{0.693}{21 min}=0.033 min^{-1}$

$\log[N]=\log[N_o]-\frac{\lambda t}{2.303}$

$\log[0.0575 g]=\log[N_o]-\frac{0.033 min^{-1}\times 252 min}{2.303}$

$N_o=234.74 grams$

The 234.74 grams of sample should be ordered.

4 0

2 years ago

What happens when: sulphuric acid reacts with zinc.

KonstantinChe [14]

Answer:

hope it helps.

Explanation:

Zinc metal dissolves slowly in dilute sulphuric acid to form solutions containing the aquated Zn(II) ion together with hydrogen gas, H2.

3 0

2 years ago

_ an electron moved around the nucleus in circular paths

kifflom [539]

Answer: although it is convenient to think of the electron moving around the nucleus along circular paths

Explanation:

7 0

2 years ago