The heat released by the water when it cools down by a temperature difference AT
is Q = mC,AT
where
m=432 g is the mass of the water
C, = 4.18J/gºC
is the specific heat capacity of water
AT = 71°C -18°C = 530
is the decrease of temperature of the water
Plugging the numbers into the equation, we find
Q = (4329)(4.18J/9°C)(53°C) = 9.57. 104J
and this is the amount of heat released by the water.
Nitrogen is 5 valence electrons
oxygen is 6 valence electrons
fluorine is 7 electrons
The protons of methylene group between the two carbonyl groups in ethylacetoacetate are acidic in nature. When compounds containing such acidic protons are treated with bases the loose proton and form enolates.
In this particular example when ethylacetoacetate is reacted with methyl magnesium bromide, the methyl group abstracts the acidic proton and converts into
methane gas. The enolate when hydrolyzed is again converted into ethylacetoacetate as shown below,