The answer to your question is false, boiling happens below the surface of a substance.
PV=nRT
P=nRT/V
P=[(0.650mol)(0.08206)(298K)]/(0.750L)=21.2atm
Remember that a conjugate acid-base pair will differ only by one proton.
None of the options you listed are conjugate acid-base pairs as none of them differ only by one proton (or H⁺)
An example of a conjugate acid-base pair would be NH₃ and NH₄⁺NH₃ + H₂O --> NH₄⁺ + OH⁻NH3 is the base, and NH₄⁺ is the conjugate acid