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fomenos
3 years ago
12

what is the reason for the difference between the values of the dry adiabatic lapse rate and the moist adiabatic lapse rate?

Chemistry
1 answer:
aalyn [17]3 years ago
6 0
Latent heat released during condensation offsets some of the cooling of a rising air parcel, causing the moist adiabatic lapse rate to have a smaller value.
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Consider the reaction: CaCO3(s) à CaO(s) + CO2(g)
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Answer:

131.5 kJ

Explanation:

Let's consider the following reaction.

CaCO₃(s) → CaO(s) + CO₂(g)

First, we will calculate the standard enthalpy of the reaction (ΔH°).

ΔH° = 1 mol × ΔH°f(CaO(s)) + 1 mol × ΔH°f(CO₂(g) ) - 1 mol × ΔH°f(CaCO₃(s) )

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ΔH° = 179.2 kJ

Then, we calculate the standard entropy of the reaction (ΔS°).

ΔS° = 1 mol × S°(CaO(s)) + 1 mol × S°(CO₂(g) ) - 1 mol × S°(CaCO₃(s) )

ΔS° = 1 mol × (38.1 J/mol.K) + 1 mol × (213.8 J/mol.K) - 1 mol × (91.7 J/mol.K)

ΔS° = 160.2 J/K = 0.1602 kJ/K

Finally, we calculate the standard Gibbs free energy of the reaction at T = 25°C = 298 K.

ΔG° = ΔH° - T × ΔS°

ΔG° = 179.2 kJ - 298 K × 0.1602 kJ/K

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