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The ph of the best buffer is 4.74
The given acetic acid is a weak acid
The equation of the pH of the buffer
pH = pKa + log ( conjugate base / weak acid ).
For best buffer the concentration of the weak acid and its conjugate base is equal.
pH = pKa + log 1
pH = pKa + 0
pH = pKa
given Ka = 1.8 × 10⁻⁵
pKa = - log ka
pH = -log ( 1.8 × 10⁻⁵ )
pH = 4. 74
Hence the pH of the best buffer is 4.74
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The number of atoms N = 5.8 x 10²¹
<h3>Further explanation</h3>
A mole is a unit of many particles (atoms, molecules, ions) where 1 mole is the number of particles contained in a substance that is the same amount as many atoms in 12 gr C-12
1 mole = 6.02.10²³ particles
mass of N in 0.82 g of NaNO₃ (MW NaNO₃: 85 g/mol) :

moles of N :

The number of atoms N :

Explanation:
Methane molecule is depicted here