a student reacted 40 drops of an unknown amine with 20 drops of iodomethane in 2 ml of a suitable solvent mixture. after 15 minu
1 answer:
The compound formed is the quaternary ammonium salt N,N,N-trimethyl-1-phenylmethanaminium iodide.
Quaternary ammonium salts are formed when methyl iodide reacts with an amine. The quaternary ammonium salt is an ionic substance which often has a high melting point. Remember that the melting point of a substance can be used to identify the substance.
In this case, a student reacted 40 drops of an unknown amine with 20 drops of iodomethane in 2 ml of a suitable solvent mixture. after 15 minutes of reaction, a white precipitate formed. the precipitate was isolated and its melting point was recorded to be 178 °c. This precipitate must be N,N,N-trimethyl-1-phenylmethanaminium iodide (Benzyltrimethylammonium iodide) because it is a quaternary ammonium salt whose melting point is 178 °c.
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Answer:
Step 1;
q = w = -0.52571 kJ, ΔS = 0.876 J/K
Step 2
q = 0, w = ΔU = -7.5 kJ, ΔH = -5.00574 kJ
Explanation:
The given parameters are;
= 100 N·m
= 327 K
= 90 N·m
Step 1
For isothermal expansion, we have;
ΔU = ΔH = 0
w = n·R·T·ln(/
) = 1 × 8.314 × 600.15 × ln(90/100) = -525.71
w ≈<em> -0.52571</em> kJ
At state 1, q = w = -0.52571 kJ
ΔS = -n·R·ln(/
) = -1 × 8.314 × ln(90/100) ≈ 0.876
ΔS ≈ 0.876 J/K
Step 2
q = 0 for adiabatic process
ΔU = 25×(27 - 327) = -7,500
w = ΔU = <em>-7.5 kJ</em>
ΔH = ΔU + n·R·ΔT
ΔH = -7,500 + 8.3142 × 300 = -5,005.74
ΔH = ΔU = <em>-5.00574 kJ</em>
This the answer have a good day
