Answer:
Explanation:
- For the balanced reaction:
<em>4Fe(s) + 3O₂(g) → 2Fe₂O₃(s).</em>
It is clear that 4 mol of Fe react with 3 mol of O₂ to produce 2 mol of Fe₂O₃.
- Firstly, we need to calculate the no. of moles of 35.8 grams of Fe metal:
no. of moles of Fe = mass/molar mass = (35.8 g)/(55.845 g/mol) = 0.64 mol.
- Now, we can find the no. of moles of O₂ is needed to react with the proposed amount of Fe:
<em><u>Using cross multiplication:</u></em>
4 mol of Fe is needed to react with → 3 mol of O₂, from stichiometry.
0.64 mol of Fe is needed to react with → ??? mol of O₂.
∴ The no. of moles of O₂ needed = (3 mol)(0.64 mol)/(4 mol) = 0.48 mol.
- Finally, we can get the volume of oxygen using the information:
<em>It is known that 1 mole of any gas occupies 22.4 L at standard P and T (STP).</em>
<em></em>
<em><u>Using cross multiplication:</u></em>
1 mol of O₂ occupies → 22.4 L, at STP conditions.
0.48 mol of O₂ occupies → ??? L.
∴ The no. of liters of O₂ = (0.48 mol)(22.4 L)/(1 mol) = 10.752 L.
Answer:
See explanation below
Explanation:
In this case we have reaction of addition. In this case a diene reacting with an acid as HBr. This reaction is known as Hydrohalogenation, and, as we have a diene, this kind of reaction can be done as 1,4 addition. Which means that the reaction will be undergoing with an adition in the carbon 1, and carbon 4.
At room temperature we can expect that this reaction can be done in thermodynamic conditions, Now, as the problem states that is forming 4 products, we can expect products of a 1,2 addition too. This product can be formed if the reaction is taking place in the most stable carbocation, and then, by resonance, we can expect the 1,4 product too.
Now, the HBr can be attacked by the double bond of the first position, giving two possible products or by the double bond of the third position giving the other two products. These products are all possible, obviously the most stable will be the major of all of them, but the other three are perfectly possible. One product is formed without doing much, and the other by resonance. Same happens with the other double bond.
In the picture below, you have the mechanism for all the 4 products.
Hope this helps
Answer:
(1) addition of HBr to 2-methyl-2-pentene
Explanation:
In this case, we will have the formation of a <u>carbocation</u> for each molecule. For molecule 1 we will have a <u>tertiary carbocation</u> and for molecule 2 we will have a <u>secondary carbocation</u>.
Therefore the <u>most stable carbocation</u> is the one produced by the 2-methyl-2-pentene. So, this molecule would react faster than 4-methyl-1-pentene. (See figure)