First we will calculate free energy change:
ΔG₀ = ΔH₀ - (T * ΔS₀)
= - 793 kJ - (298 * - 0.319 kJ/K) = - 698 kJ
We know the relation between free energy change and cell potential is:
ΔG₀ = - n F E⁰ where
F = Faraday's constant = 96485 C/mol
n = 2 (given by equation that the electrons involved is 2)
ΔG₀ = - 2 x 96485 x E⁰
- 698 kJ = - 2 x 96485 x E⁰
E⁰ = (698 x 1000) / (2 x 96485) = 3.62 volts
The partial atmospheric pressure (atm) of hydrogen in the mixture is 0.59 atm.
<h3>How do we calculate the partial pressure of gas?</h3>
Partial pressure of particular gas will be calculated as:
p = nP, where
- P = total pressure = 748 mmHg
- n is the mole fraction which can be calculated as:
- n = moles of gas / total moles of gas
Moles will be calculated as:
- n = W/M, where
- W = given mass
- M = molar mass
Moles of Hydrogen gas = 2.02g / 2.014g/mol = 1 mole
Moles of Chlorine gas = 35.90g / 70.9g/mol = 0.5 mole
Mole fraction of hydrogen = 1 / (1+0.5) = 0.6
Partial pressure of hydrogen = (0.6)(748) = 448.8 mmHg = 0.59 atm
Hence, required partial atmospheric pressure of hydrogen is 0.59 atm.
To know more about partial pressure, visit the below link:
brainly.com/question/15302032
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