To determine which order of the reaction it is, first we need to calculate the rate of change of moles.
the data is as follows
time 0 40 80 120 160
moles 0.100 0.067 0.045 0.030 0.020
Q1)
for the first 40 s change of moles ;
= -d[A] / t
= - (0.067-0.100)/40s
= 8.25 x 10⁻⁴ mol/s
for the next 40 s
= -(0.045-0.067)/40
= 5.5 x 10⁻⁴ mol/s
the 40 s after that
= -(0.030-0.045)/40 s
= 3.75 x 10⁻⁴ mol/s
k - rate constant
and A is the only reactant that affects the rate of the reaction
rate = k [A]ᵇ
8.25 × 10⁻⁴ mol/s = k [0.100 mol]ᵇ ----1
5.5 x 10⁻⁴ mol/s = k [0.067 mol]ᵇ -----2
divide the 2nd equation by the 1st equation
1.5 = [1.49]ᵇ
b is almost equal to 1
Therefore this is a first order reaction
Q2)
to find out the rate constant(k), we have to first state the equation for a first order reaction.
rate = k[A]ᵇ
As A is the only reactant thats considered for the rate equation.
Since this is a first order reaction,
b = 1
therefore the reaction is
rate = k[A]
substituting the values,
8.25 x 10⁻⁴ mol/s = k [0.100 mol]
k = 8.25 x 10⁻⁴ mol/s /0.100mol
= 8.25 x 10⁻³ s⁻¹
The periodic table of the elements are describe the electronic configuration of the elements on which the properties of the elements depends. Among the given groups only metal, non-metal and semi-metal group are the part of periodic table. The metallic property depends upon the binding energy of the electrons with the nucleus. Thus the elements which have the valence electrons more near to the nucleus that is s-block elements are more metallic in nature. On the other hand the elements which have the valence electrons far from the nucleus are more non-metallic in nature like p-block elements. However the binding energy or the attraction of the outermost electrons to the nucleus depends not only its valence electrons position but also some other factors like shielding effect, effective nuclear charge etc.
The elements which are in between the metals and non-metals can be classified as semi-metals.
Although the conductivity of a material is an inherent property of the metals but sometime the nonmetals or semi-metals are also behave like a conductor due to presence of the other elements, thus it cannot be a p[property of the periodic table. Similarly acidity, flammable gases are not part of the periodic table.
Answer:
Mole fraction of solute is 0.0462
Explanation:
To solve this we use the colligative property of lowering vapor pressure.
First of all, we search for vapor pressure of pure water at 25°C = 23.8 Torr
Now, we convert the Torr to mmHg. Ratio is 1:1, so 23.8 Torr is 23.8 mmHg.
Formula for lowering vapor pressure is:
ΔP = P° . Xm
Where ΔP = P' (Vapor pressure of solution) - P° (Vapor pressure of pure solvent)
Xm = mole fraction
24.9 mmHg - 23.8 mmHg = 23mmHg . Xm
Xm = (24.9 mmHg - 23.8 mmHg) / 23mmHg
Xm = 0.0462
Using Phosphoric acid will work perfectly for producing Hydrogen halides because its not an Oxidizing agent. ...
Using an ionic chloride and Phosphoric acid
H3PO4 + NaCl ==> HCl + NaH2PO4
H3PO4 + NaI ==> HI + NaH2PO4
H2SO4 + NaCl ==> HCl + NaHSO4
This method(Using H2So4) will work for all hydrogen hydrogen halide except Hydrogen Iodide and Hydrogen Bromide.
The Sulphuric acid won't be useful for producing Hydrogen Iodide because its an OXIDIZING AGENT. Whist producing the Hydrogen Iodide... Some of the Iodide ions are oxidized to Iodine.
2I-² === I2 + 2e-
Answer:
Explanation:
- overall order is also first order
Since we are told that CH3OH is the solvent for the reaction, as such the rate law equation will only be written for (CH3)3CCl .
