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Take east to be the positive direction. Then the resultant force from adding <em>F</em>₁ and <em>F</em>₂ is
<em>F</em>₁ + <em>F</em>₂ = (-45 N) + 63 N = 18 N
which is positive, so it's directed east.
To this we add a third force <em>F</em>₃ such that the resultant is 12 N pointing west, making it negative, so that
18 N + <em>F</em>₃ = -12 N
<em>F</em>₃ = -30 N
So <em>F</em>₃ has a magnitude of 30 N and points west.