On combustion of 0.2 gm of organic compound gave 0.147g of CO2, 0.12g of H2O and 74.6 ml of nitrogen gas at STP. Find emperical
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If you place 1.0 L of ethanol (C2H5OH) in a small laboratory that is 3.0 m long, 2.0 m wide, and 2.0 m high, will all the alcohol evaporate? If some liquid remains, how much will there be? The vapor pressure of ethyl alcohol at 25 °C is 59 mm Hg, and the density of the liquid at this temperature is 0.785g/cm^3 .
will all the alcohol evaporate? or none at all?
Answer:
Yes, all the ethanol present in the laboratory will evaporate since the mole of ethanol present in vapor is greater. The volume of ethanol left will therefore be zero.
Explanation:
Given that:
The volume of alcohol which is placed in a small laboratory = 1.0 L
Vapor pressure of ethyl alcohol at 25 ° C = 59 mmHg
Converting 59 mmHg to atm ; since 1 atm = 760 mmHg;
Then, we have:
=
= 0.078 atm
Temperature = 25 ° C
= ( 25 + 273 K)
= 298 K.
Density of the ethanol = 0.785 g/cm³
The volume of laboratory = l × b × h
= 3.0 m × 2.0 m × 2.5 m
= 15 m³
Converting the volume of laboratory to liter;
since 1 m³ = 100 L; Then, we have:
15 × 1000 = 15,000 L
Using ideal gas equation to determine the moles of ethanol in vapor phase; we have:
PV = nRT
Making n the subject of the formula; we have:
n = 47. 88 mol of ethanol
Moles of ethanol in 1.0 L bottle can be calculated as follows:
Since numbers of moles =
and mass = density × vollume
Then; we can say ;
number of moles =
number of moles =
number of moles =
number of moles = 17.039 mol
Thus , all the ethanol present in the laboratory will evaporate since the mole of ethanol present in vapor is greater. The volume of ethanol left will therefore be zero.
The frequency of the radiation is equal to Hertz.
<u>Given the following data:</u>
- Photon energy =
Joules
To find the frequency of this radiation, we would use the Planck-Einstein equation.
Mathematically, the Planck-Einstein relation is given by the formula:
<u>Where:</u>
- h is Planck constant.
- f is photon frequency.
Substituting the given parameters into the formula, we have;
Frequency, F = Hertz
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