The first step of the oxidation of a primary alcohol involves conversion to an aldehyde via the elimiination of a hydrogen molecule. Thus, ClCH2CH2CH2OH becomes ClCH2CH2COH, which is 3-chloropropanal.
Answer:
The value of Q must be less than that of K.
Explanation:
The difference of K and Q can be understood with the help of an example as follows
A ⇄ B
In this reaction A is converted into B but after some A is converted , forward reaction stops At this point , let equilibrium concentration of B be [B] and let equilibrium concentration of A be [A]
In this case ratio of [B] and [A] that is
K = [B] / [A] which is called equilibrium constant.
But if we measure the concentration of A and B ,before equilibrium is reached , then the ratio of the concentration of A and B will be called Q. As reaction continues concentration of A increases and concentration of B decreases. Hence Q tends to be equal to K.
Q = [B] / [A] . It is clear that Q < K before equilibrium.
If Q < K , reaction will proceed towards equilibrium or forward reaction will
proceed .
Answers and Explanation:
a)- The chemical equation for the corresponden equilibrium of Ka1 is:
2. HNO2(aq)⇌H+(aq)+NO−2
Because Ka1 correspond to a dissociation equilibrium. Nitrous acid (HNO₂) losses a proton (H⁺) and gives the monovalent anion NO₂⁻.
b)- The relation between Ka and the free energy change (ΔG) is given by the following equation:
ΔG= ΔGº + RT ln Q
Where T is the temperature (T= 25ºc= 298 K) and R is the gases constant (8.314 J/K.mol)
At the equilibrium: ΔG=0 and Q= Ka. So, we can calculate ΔGº by introducing the value of Ka:
⇒ 0 = ΔGº + RT ln Ka
ΔGº= - RT ln Ka
ΔGº= -8.314 J/K.mol x 298 K x ln (4.5 10⁻⁴)
ΔGº= 19092.8 J/mol
c)- According to the previous demonstation, at equilibrium ΔG= 0.
d)- In a non-equilibrium condition, we have Q which is calculated with the concentrations of products and reactions in a non equilibrium state:
ΔG= ΔGº + RT ln Q
Q= ((H⁺) (NO₂⁻))/(HNO₂)
Q= ( (5.9 10⁻² M) x (6.7 10⁻⁴ M) ) / (0.21 M)
Q= 1.88 10⁻⁴
We know that ΔGº= 19092.8 J/mol, so:
ΔG= ΔGº + RT ln Q
ΔG= 19092.8 J/mol + (8.314 J/K.mol x 298 K x ln (1.88 10⁻⁴)
ΔG= -2162.4 J/mol
Notice that ΔG<0, so the process is spontaneous in that direction.
Answer:
c I've taken chem 3 times
Explanation:
