When the temperature of a gas within a rigid container decreases, the particles on average move more slowly and do not collide with one another or the container walls as often. It is the the ideal gas law that applies in this situation and states that a decrease in the temperature of a gas also results in a decrease in the pressure. Thus, automobile tyres which have a colder gas in the winter sometimes need additional air to provide suffiicient pressure.
Answer:
sp³d¹ hybridization
Explanation:
Given Cl as central element with three F substrates ...
The VSEPR structure indicates 5 hybrid orbitals that contain 2 diamagnetic orbitals (non-bonded e⁻-pairs) and 3 paramagnetic orbitals (single, non-paired electron for covalent bonding with fluorine) giving a trigonal bypyrimidal parent with a T-shaped geometry.
Valence bond theory predicts the following during bonding:
Cl:[Ne]3s²3p²p²p¹3d⁰
=> [Ne]3s²p²p¹p¹d¹
=> [Ne]3(sp³d)²(sp³d)²(sp³d)¹(sp³d)¹(sp³d)¹
giving 3 ( [Cl](sp³d) - [F]2p¹ ) sigma bonds and 2 non-bonded pairs on Cl.
Note the following images:
Non-bonded electron pairs are in plane of parent geometry and Fluorides covalently bonded to central element Chloride forming the T-shaped geometry.
Neo-pentane represents the Compound A while compound B is n-pentane.
After careful consideration we can say that compounds A and B are alkanes and also isomers of pentane. In chemistry, Isomers are defined as compounds having same empirical molecular formula but different structural formulas due to varying arrangement of atoms.
Now, as per the question statement, compound A gives a single monochlorination product upon heating with the molecule of chlorine i.e. Cl2 showing that the molecule is extremely symmetric. This molecule must be neo-pentane. Refer to image 1.
Similarly, Compound B forms 3 constitutional isomers after undergoing monochlorination. This compound must be n-pentane since three are 3 different types of carbon atoms in the structure. Refer to image 2.
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You should never touch the subscripts, as that will change the composition. Hope I helped!
Li2CO3 + 2HNO3 ----> 2LiNO3 + H2O + CO2