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Chemistry

2 answers:

Ipatiy [6.2K]2 years ago

6 0

Answer:

Explanation:

B is UR answer

anastassius [24]2 years ago

4 0

Answer:

B: They are the results of many experiments over a long period of time.

Explanation:

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what is the pH of a solution prepared from solid, neutral 2-nitrophenol providing a fromal concentration of 0.0353M, given that

REY [17]

Answer:

pH = 4.34

Explanation:

pH= -1/2(logKa) -1/2(log C)

= -1/2( log 5.98*10^-8) -1/2(log 0.0353)

=-1/2(-7.22)-1/2(-1.45)

=3.61+0.725= 4.34

7 0

3 years ago

Suppose you have just added 100 ml of a solution containing 0.5 mol of acetic acid per liter to 400 ml of 0.5 m naoh. what is th

Tpy6a [65]

$pH = 13.5$

Explanation:

Sodium hydroxide completely ionizes in water to produce sodium ions and hydroxide ions. Hydroxide ions are in excess and neutralize all acetic acid added by the following ionic equation:

$\text{HAc} + \text{OH}^{-} \to \text{Ac}^{-} + \text{H}_2\text{O}$

The mixture would contain

$0.4 \times 0.5 - 0.1 \times 0.5 = 0.15 \; \text{mol}$ of $\text{OH}^{-}$ and
$0.1 \times 0.5 = 0.05 \; \text{mol}$ of $\text{Ac}^{-}$

if $\text{Ac}^{-}$ undergoes no hydrolysis; the solution is of volume $0.1 + 0.4 = 0.5 \; \text{L}$ after the mixing. The two species would thus be of concentration $0.30 \; \text{mol} \cdot \text{L}^{-1}$ and $0.10 \; \text{mol} \cdot \text{L}^{-1}$ , respectively.

Construct a RICE table for the hydrolysis of $\text{Ac}^{-}$ under a basic aqueous environment (with a negligible hydronium concentration.)

$\begin{array}{cccccccc} \text{R} & \text{Ac}^{-}(aq) &+ & \text{H}_2\text{O}(aq) & \leftrightharpoons & \text{HAc}(aq) & + & \text{OH}^{-} (aq)\\ \text{I} & 0.10 \; \text{M} & & & & & &0.30 \; \text{M}\\ \text{C} & -x \; \text{M}& & & & +x \; \text{M}& & +x \; \text{M} \\ \text{E} & (0.10 - x) \; \text{M} & & & & x \; \text{M} & & (0.30 +x) \; \text{M} \end{array}$

The question supplied the <em>acid</em> dissociation constant $pK_a$ for acetic acid $\text{HAc}$ ; however, calculating the hydrolysis equilibrium taking place in this basic mixture requires the <em>base</em> dissociation constant $pK_b$ for its conjugate base, $\text{Ac}^{-}$ . The following relationship relates the two quantities:

$pK_{b} (\text{Ac}^{-}) = pK_{w} - pK_{a}( \text{HAc})$

... where the water self-ionization constant $pK_w \approx 14$ under standard conditions. Thus $pK_{b} (\text{Ac}^{-}) = 14 - 4.7 = 9.3$ . By the definition of $pK_b$ :