Answer: CoBr3 < K2SO4 < NH4 Cl
Justification:
1) The depression of the freezing point of a solution is a colligative property, which means that it depends on the number of particles of solute dissolved.
2) The formula for the depression of freezing point is:
ΔTf = i * Kf * m
Where i is the van't Hoof factor which accounts for the dissociation of the solute.
Kf is the freezing molal constant and only depends on the solvent
m is the molality (molal concentration).
3) Since, you are assuming equal concentrations and complete dissociation of the given solutes, the solute with more ions in the molecular formula will result in the solution with higher depression of the freezing point (lower freezing point).
4) These are the dissociations of the given solutes:
a) NH4 Cl (s) --> NH4(+)(aq) + Cl(-) (aq) => 1 mol --> 2 moles
b) Co Br3 (s) --> Co(3+) (aq) + 3Br(-)(aq) => 1 mol --> 4 moles
c) K2SO4 (s) --> 2K(+) (aq) + SO4 (2-) (aq) => 1 mol --> 3 moles
5) So, the rank of solutions by their freezing points is:
CoBr3 < K2SO4 < NH4 Cl
Answer:

Explanation:
Hello there!
In this case, according to the given STP (standard pressure and temperature), it is possible for us to realize that the equation to use here is the Avogadro's law as a directly proportional relationship between moles and volume:

In such a way, given the initial volume and both initial and final moles, we can easily compute the final volume as shown below:

Best regards!