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1 mole of nitric acid produce 1 mole of ammonium nitrate.
moles in 5000 kg of ammonium nitrate :
( molecular mass of ammonium nitrate is 80 gm/mol )
So, number of moles of nitric acid required are also 62500 moles.
Mass of 62500 moles of nitric acid :
Hence, this is the required solution.