The amount of N2O5 to start with would be 35.79 grams
<h3>Stoichiometric calculations</h3>
From the balanced equation of the reactions:

Mole ratio of N2O5 and NO2 = 1:2
Since the reaction's actual yield is 82%, the theoretical yield would be: 25 x 100/82 = 30.49 grams
Mole of 25 g NO2 = 30.49/46
= 0.66 mole
Equivalent mole of N2O5 = 0.54/2 mole
= 0.33 moles
Mass of 0.27 mole N2O5 = 0.33 x 108.01
= 35.79 grams
More on stoichiometric calculations can be found here: brainly.com/question/8062886