1.00
Explanation:
the density of water is always 1
1) Chemical reaction
HCl + NaOH ---> NaCl + H2O
25.0 ml
0.150 M 0.250M
2) 50% completion => 0.025 l * 0.150 M * (1/2) = 0.001875 mol HCl consumed and 0.001875 mol HCl in solution
0.001875 mol HCl => 0.001875 mol H(+)
Volume = Volume of HCl solution + Volumen of NaOH solution added
Volume of HCl solution = 0.0250 l
Volume of NaOH = n / M = 0.001875 mol / 0.250M = 0.0075 l
Total volume = 0.0250 l + 0.0075 l = 0.0325 l
[H+] = 0.001875 mol / 0.0325 l = 0.05769 M
pH = - log [H+] = - log (0.05769) = 1.23
Answer: 1.23
3) Equivalence point
0.02500 l * 0.150 M = 0.250M * V
=> V = 0.02500 * 0.150 / 0.250 = 0.015 l
4) 1.00 ml NaOH added beyond the equivalence point
1.00 ml * 1 l / 1000 ml * 0.250 M = 0.00025 mol NaOH in excess
0.00025 mol NaOH = 0.00025 mol OH-
Volume of the solution = 0.02500 l + 0.015 l + 1.00/1000 l = 0.041 l
[OH-] = 0.00025 mol / 0.041 l = 0.00610 M
pOH = - log (0.00610) = 2.21
pH + pOH = 14 => pH = 14 - pOH = 14 - 2.21 = 11.76
Answer: 11.76
2 SO₃ --> 2 SO₂ + O₂
I 12 0 0
C -2x +2x +x
---------------------------------------------
E 12-2x 2x x
Since the moles of SO₂ at equilibrium is 3 mol, 2x = 3. Then, x = 1.5 mol. So, the amounts at equilibrium is:
SO₃: 12 - 2(1.5) = 9
SO₂: 2(1.5) = 3
O₂: 1.5
The formula for K basing on the stoichiometric reaction is:
K = [SO₂]²[O₂]/[SO₃]²
where the unit used is conc in mol/L.
K = [3 mol/3 L]²[1.5 mol/3 L]/[9 mol/3 L]²
<em>K = 0.0556</em>
<span>Soda ash is sodium carbonate, Na2CO3. One chemical property of this compound is its basicity, which is measured by the pKb. The pKb for sodium carbonate is 3.67. It is the result of the dissociation of Na2CO3 in water: Na2CO3 + H2O = Na HCO3 + Na (+) + OH(-). This pKb means that it is a highly basic compound. pKb = log { 1 / [OH-] }, so pKb is a measure of the concentrations of OH- ions, which is the basiciity of the compound. </span>
