Answer:
E. None of these
Explanation:
We know, By GAS laws,
PV = NRT, where p- pressure, v- volume, n- number of moles, R- gas constant ,and T- temperature
Now, In the question, the number of moles remains the same as the gas is the same. so n is constant so we can compare n before and after a temperature change.
= 
where P1= 1 atm, P2 = 10 atm, V1= 20 mL, T1= 10°C and T2= 100°C
We don't have to worry about the standard units as they are present equally on both the sides and get cut, same goes for R( gas constant)
So putting values, we get
Cutting, R on both sides and moving contents to the right so that only V2 is left on the left.
∴ V2 = 
∴ V2 = 20mL
Answer:
0.14 M
Explanation:
To determinate the concentration of a new solution, we can use the equation below:
C1xV1 = C2xV2
Where C is the concentration, and V the volume, 1 represents the initial solution, and 2 the final one. So, first, the initial concentration is 1.50 M, the initial volume is 55.0 mL and the final volume is 278 mL
1.50x55.0 = C2x278
C2 = 0.30 M
The portion of 139 mL will be the same concentration because it wasn't diluted or evaporated. The final volume will be the volume of the initial solution plus the volume of water added, V2 = 139 + 155 = 294 mL
Then,
0.30x139 = C2x294
C2 = 0.14 M
Answer:
customary Is the required system
Answer:
Here's what I get
Explanation:
You may have done a Williamson synthesis of guaifenesin by reacting guaiacol with 3-chloropropane-1,2-diol.
A. Mechanism
Step 1
NaOH converts guaiacol into a phenoxide ion.
Step 2
The phenoxide acts as the nucleophile in an SN2 reaction to displace the Cl from the alkyl halide.
B. Improve the yield
You probably carried out the reaction in ethanol solution — a polar protic solvent.
You might try doing the reaction in a polar aprotic solvent— perhaps DMSO.
A polar aprotic solvent does not hydrogen bond to nucleophiles, so they become stronger.
C. Another method of ether synthesis —dehydration of alcohols
Sulfuric acid catalyzes the conversion of primary alcohols to ethers.
This is also a nucleophilic displacement reaction.
Protonation of the OH converts it into a better leaving group.
Attack by a second molecule of alcohol forms the protonated ether.
A molecule of water then removes the proton.
