Answer:
Option (E) is correct
Explanation:
Solubility equilibrium of 
is given as follows-
Hence, if solubility of is S (M) then-
![[Pb^{2+}]=S(M)](https://tex.z-dn.net/?f=%5BPb%5E%7B2%2B%7D%5D%3DS%28M%29)
and ![[IO_{3}^{-}]=2S(M)](https://tex.z-dn.net/?f=%5BIO_%7B3%7D%5E%7B-%7D%5D%3D2S%28M%29)
Where species under third bracket represent equilibrium concentrations
So, solubility product of , ![K_{sp}=[Pb^{2+}][IO_{3}^{-}]^{2}](https://tex.z-dn.net/?f=K_%7Bsp%7D%3D%5BPb%5E%7B2%2B%7D%5D%5BIO_%7B3%7D%5E%7B-%7D%5D%5E%7B2%7D)
Here, ![[Pb^{2+}]=S(M)=5.0\times 10^{-5}M](https://tex.z-dn.net/?f=%5BPb%5E%7B2%2B%7D%5D%3DS%28M%29%3D5.0%5Ctimes%2010%5E%7B-5%7DM)
So, ![[IO_{3}^{-}]=2S(M)=(2\times 5.0\times 10^{-5})M=1.0\times 10^{-4}M](https://tex.z-dn.net/?f=%5BIO_%7B3%7D%5E%7B-%7D%5D%3D2S%28M%29%3D%282%5Ctimes%205.0%5Ctimes%2010%5E%7B-5%7D%29M%3D1.0%5Ctimes%2010%5E%7B-4%7DM)
So, 
Hence option (E) is correct
Answer:
See explanation
Explanation:
The balanced redox reaction equation is;
8H+ + MnO4^- + 5Fe2+ ---------> Mn2+ + 5Fe3+ + 4H2O
Amount of KMnO4 reacted = 31.60/1000 * 0.05120 = 1.62 * 10^-3 moles
From the reaction equation;
1 mole of MnO4^- reacted with 5 moles of Fe2+
1.62 * 10^-3 moles will react with 1.62 * 10^-3 moles * 5/1 = 8.1 * 10^-3 moles
Mass of Fe2+ reacted = 8.1 * 10^-3 moles * 56 g/mol
Mass of Fe2+ reacted = 0.45 g
Amount of iron in the sample = 0.45 g
Percentage of iron in the sample;
0.45 g/4.230 g * 100 = 10.6 %
Answer:
p-fluoronitrobenzene and sodium phenoxide is more appropriate
Explanation:
An ipso substitution is required to form p-nitrophenyl phenyl ether.
For this ipso substitution, an alkoxide anion needs to attack as a nucleophile at the carbon atom attached to fluorine atom and thereby substitute that F atom.
p-nitrophenoxide is an weak nucleophile as compared to phenoxide due to presence of electron withdrawing resonating effect of nitro group at para position.
p-fluoronitrobenzene is a good choice for nucleophilic attack by alkoxide anion as compared to fluorobenzene due to higher positive charge density at carbon atom directly attached to F atom. Higher positive charge density arises due to presence of electron withdrawing resonating effect og nitro group at para position.
So, p-fluoronitrobenzene and sodium phenoxide is more appropriate
Answer:
1.67mol/L
Explanation:
Data obtained from the question include:
Mole of solute (K2CO3) = 5.51 moles
Volume of solution = 3.30 L
Molarity =?
Molarity is simply the mole of solute per unit litre of the solution. It can be expressed mathematically as:
Molarity = mole of solute /Volume of solution
Molarity = 5.51 mol/3.30 L
Molarity = 1.67mol/L
Therefore, the molarity of K2CO3 is 1.67mol/L
Answer is: glycerol because it is more viscous and has a larger molar mass.
Viscosity depends on intermolecular interactions.
The predominant intermolecular force in water and glycerol is hydrogen bonding.
Hydrogen bond is an electrostatic attraction between two polar groups in which one group has hydrogen atom (H) and another group has highly electronegative atom such as nitrogen (like in this molecule), oxygen (O) or fluorine (F).
