Calculate the number of moles when 3.00l of a gas at 814 mmhg and 25 °c?
1 answer:
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Answer:
See explanation
Explanation:
The reaction that we are considering here is quite a knotty reaction. It is difficult to decide if the mechanism is actually E1 or E2 since both are equally probable based on the mass of scientific evidence regarding this reaction. However, we can easily assume that the methylenecyclohexane was formed by an E1 mechanism.
Looking at the products, one could convincingly assert that the reaction leading to the formation of the two main products proceeds via an E1 mechanism with the formation of a carbocation intermediate as has been shown in mechanism attached to this answer. Possible rearrangement of the carbocation yields the 3-methylcyclohexene product.
Answer:
1. Exothermic.
2. -1598 kJ.
Explanation:
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1. In this case, according to the reaction, we can infer that 799 kJ of energy are evolved (given off, released) it means that the enthalpy of reaction is negative as the reactants have more energy than the products; which means this is an exothermic reaction.
2. Here, as we know that the enthalpy of reaction is -799 kJ/mol, we can compute the q-value as shown below, considering the reacted 2 moles of solid iron:
Which means that 1598 kJ of energy are evolved when 2 moles of solid iron react.
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