Solve 21 and 22 please

A student isolated 7.2 g of 1-bromobutane reacting equimolar amounts of 1-butanol (10 ml) and NaBr (11.1 g) in the presence of s

Alla [95]

Answer: The percent yield of the 1-bromobutane is 48.65 %

Explanation:

To calculate the number of moles, we use the equation:

$\text{Number of moles}=\frac{\text{Given mass}}{\text{Molar mass}}$ .....(1)

For NaBr:

Given mass of NaBr = 11.1 g

Molar mass of NaBr = 103 g/mol

Putting values in equation 1, we get:

$\text{Moles of NaBr}=\frac{11.1g}{103g/mol}=0.108mol$

The chemical equation for the reaction of 1-butanol and NaBr is:

$\text{1-butanol + NaBr}\rightarrow \text{1-bromobutane}$

By Stoichiometry of the reaction

1 mole of NaBr produces 1 mole of 1-bromobutane

So, 0.108 moles of NaBr will produce = $\frac{1}{1}\times 0.108=0.108$ moles of 1-bromobutane

Now, calculating the mass of 1-bromobutane from equation 1, we get:

Molar mass of 1-bromobutane = 137 g/mol

Moles of 1-bromobutane = 0.108 moles

Putting values in equation 1, we get:

$0.108mol=\frac{\text{Mass of 1-bromobutane}}{137g/mol}\\\\\text{Mass of 1-bromobutane}=(0.108mol\times 137g/mol)=14.80g$

To calculate the percentage yield of 1-bromobutane, we use the equation:

$\%\text{ yield}=\frac{\text{Experimental yield}}{\text{Theoretical yield}}\times 100$

Experimental yield of 1-bromobutane = 7.2 g

Theoretical yield of 1-bromobutane = 14.80 g

Putting values in above equation, we get:

$\%\text{ yield of 1-bromobutane}=\frac{7.2g}{14.80g}\times 100\\\\\% \text{yield of 1-bromobutane}=48.65\%$

Hence, the percent yield of the 1-bromobutane is 48.65 %

5 0

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Ede4ka [16]

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Oksanka [162]

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4 0

3 years ago

1.86 g H2 is allowed to react with 9.75 g N2 , producing 2.87g NH3.

svet-max [94.6K]

Answer:

(a) Theoretical Yield = 10.50 g

(b) %age yield = 27.33 %

Explanation:

Answer-Part-(a)

The balance chemical equation for the synthesis of Ammonia is as follow;

N₂ + 3 H₂ → 2 NH₃

Step 1: Calculating moles of N₂ as;

Moles = Mass / M/Mass

Moles = 9.75 g / 28.01 g/mol

Moles = 0.348 moles of N₂

Step 2: Calculating moles of H₂ as;

Moles = Mass / M/Mass

Moles = 1.86 g / 2.01 g/mol

Moles = 0.925 moles

Step 3: Finding Limiting reagent as;

According to equation,

1 mole of N₂ reacts with = 3 moles of H₂

So,

0.348 moles of N₂ will react with = X moles of H₂

Solving for X,

X = 3 mol × 0.348 mol / 1 mol

X = 1.044 mol of H₂

It shows that to consume 0.348 moles of N₂ completely we require 1.044 mol of Hydrogen while, as given in statement we are only provided with 0.925 moles of H₂ hence, hydrogen is limiting reagent. Therefore, H₂ will control the final yield.

Step 4: Calculating moles of Ammonia as,

According to equation,

3 mole of H₂ produces = 2 moles of NH₃

So,

0.925 moles of H₂ will produce = X moles of NH₃

Solving for X,

X = 2 mol × 0.925 mol / 3 mol

X = 0.616 mol of NH₃

Step 5: Calculating theoretical yield of Ammonia as,

Theoretical Yield = Moles × M.Mass

Theoretical Yield = 0.616 mol × 17.03 g/mol

Theoretical Yield = 10.50 g

Answer-Part-(b)

%age yield = Actual Yield / Theoretical Yield × 100

%age yield = 2.87 g / 10.50 g × 100

%age yield = 27.33 %

4 0

3 years ago