First a balanced reaction equation must be established:

→

Now if mass of aluminum = 145 g
the moles of aluminum = (MASS) ÷ (MOLAR MASS) = 145 g ÷ 30 g/mol
= 4.83 mols
Now the mole ratio of Al : O₂ based on the equation is 4 : 3
[
4Al +
3 O₂ → 2 Al₂O₃]
∴ if moles of Al = 4.83 moles
then moles of O₂ = (4.83 mol ÷ 4) × 3
=
3.63 mol (to 2 sig. fig.)
Thus it can be concluded that
3.63 moles of oxygen is needed to react completely with 145 g of aluminum.
To determine the amount of a substance in units of moles from units of grams, we need to determine the molar mass of the substance. <span>The </span>molar mass<span> is the </span>mass<span> of a given chemical element or chemical compound (g) divided by the amount of substance (mol). For CuF2, the molar mass </span><span>101.543 g/mol. We calculate as follows:
100.0 g CuF2 ( 1 mol / 101.543 g) = 0.98 mol CuF2</span>
The rate constant of first order reaction at 32. 3 °C is 0.343 /s must be less the 0. 543 at 25°C.
First-order reactions are very commonplace. we have already encountered examples of first-order reactions: the hydrolysis of aspirin and the reaction of t-butyl bromide with water to present t-butanol. every other reaction that famous obvious first-order kinetics is the hydrolysis of the anticancer drug cisplatin.
The value of ok suggests the equilibrium ratio of products to reactants. In an equilibrium combination both reactants and merchandise co-exist. big ok > 1 merchandise are k = 1 neither reactants nor products are desired.
Rate constant K₁ = 0. 543 /s
T₁ = 25°C
Activation energy Eₐ = 75. 9 k j/mol.
T₂ = 32. 3 °C.
K₂ =?
formula;
log K₂/K₁= Eₐ /2.303 R [1/T₁ - 1/T₂]
putting the value in the equation
K₂ = 0.343 /s
Hence, The rate constant of first order reaction at 32. 3 °C is 0.343 /s
The specific rate steady is the proportionality consistent touching on the fee of the reaction to the concentrations of reactants. The fee law and the specific charge consistent for any chemical reaction should be determined experimentally. The cost of the charge steady is temperature established.
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