Answer:
The relation between the shielding and effective nuclear charge is given as

where s denote shielding
z_{eff} denote effective nuclear charge
Z - atomic number
Explanation:
shielding is referred to as the repulsion of an outermost electron to the pull of electron from valence shell. Higher the electron in valence shell higher will be the shielding effects.
Effective nuclear charge is the amount of net positive charge that valence electron has.
The relation between the shielding and the effective nuclear charge is given as
wheres denote shielding
z_{eff} denote effective nuclear charge
Z - atomic number
The products are on the right side of the equation. For this one it would be 2AlPO4 + 3CaSO4
You can't usually just use a single spectrum line to confirm the identity of an element because there are cases that the emission line id not clearly defined. When the emission line is very weak compared to surrounding noise, in which case the more datapoints you have to build up confidence for the existence of a particular emission spectra, the better.