Answer:
Explanation:
a).
conc of Ca²⁺ =0.0025 M
pCa = -log(0.0025) = 2.6
logK,= 10.65 So lc = 4.47 x 10.
Formation constant of Ca(EDTA)]-z= 4.47 x 10¹⁰ At pH = 11, the fraction of EDTA that exists Y⁻⁴ is
=0.81
So the Conditional Formation constant=
=0.81x 4.47 x10¹⁰
=3.62x10¹⁰
b)
At Equivalence point:
Ca²⁺ forms 1:1 complex with EDTA At equivalence point,
Number of moles of Ca²⁺= Number of moles of EDTA Number of moles of Ca²⁺ = M×V = 0.00250 M × 50.00 mL = 0.125 mol
Number of moles of EDTA= 0.125 mol
Volume of EDTA required = moles/Molarity = 0.125 mol / 0.0050 M = 25.00 mL
V e= 25.00 mL
At equivalence point, all Ca²⁺ is converted to [CaY²⁻] complex. So the concentration of Ca²⁺ is determined by the dissociation of [CaY²⁻] complex.
![[CaY^{2-}] = \frac{Initial,moles,of, Ca^{2+}}{Total,Volume} = \frac{0.125mol}{(50.00+25.00)mL} = 0.001667M](https://tex.z-dn.net/?f=%5BCaY%5E%7B2-%7D%5D%20%3D%20%5Cfrac%7BInitial%2Cmoles%2Cof%2C%20Ca%5E%7B2%2B%7D%7D%7BTotal%2CVolume%7D%20%3D%20%5Cfrac%7B0.125mol%7D%7B%2850.00%2B25.00%29mL%7D%20%3D%200.001667M)

Ca²⁺ + Y⁴ ⇄ CaY²⁻
Initial 0 0 0.001667
change +x +x -x
equilibrium x x 0.001667 - x
![{K^'}_f = \frac{[CaY^{2-}]}{[Ca^{2+}][Y^4]}=\frac{0.001667-x}{x.x} =\frac{0.001667-x}{x^2}\\\\x^2 = \frac{0.001667-x}{{K^'}_f}\\ \\](https://tex.z-dn.net/?f=%7BK%5E%27%7D_f%20%3D%20%5Cfrac%7B%5BCaY%5E%7B2-%7D%5D%7D%7B%5BCa%5E%7B2%2B%7D%5D%5BY%5E4%5D%7D%3D%5Cfrac%7B0.001667-x%7D%7Bx.x%7D%20%3D%5Cfrac%7B0.001667-x%7D%7Bx%5E2%7D%5C%5C%5C%5Cx%5E2%20%3D%20%5Cfrac%7B0.001667-x%7D%7B%7BK%5E%27%7D_f%7D%5C%5C%20%5C%5C)

x = 2.15×10⁻⁷
[Ca+2] = 2.15x10⁻⁷ M
pca = —log(2 15x101= 6.7
Answer:
Both are endothermic reactions.
Explanation:
Chemical equation:
1/2H₂(g) + 1/2I₂(g) → HI(g) + 6.2 kcal/mol
Chemical equation:
21.0 kcal/mol + C(s) + 2S(s) → CS₂
Both reaction are endothermic because heat is added in both of reactions.
Endothermic reactions:
The type of reactions in which energy is absorbed are called endothermic reactions.
In this type of reaction energy needed to break the bond are higher than the energy released during bond formation.
For example:
C + H₂O → CO + H₂
ΔH = +131 kj/mol
it can be written as,
C + H₂O + 131 kj/mol → CO + H₂
Exothermic reaction:
The type of reactions in which energy is released are called exothermic reactions.
In this type of reaction energy needed to break the bonds are less than the energy released during the bond formation.
For example:
Chemical equation:
C + O₂ → CO₂
ΔH = -393 Kj/mol
it can be written as,
C + O₂ → CO₂ + 393 Kj/mol
The energy released in nuclear reactions are far larger than that released in chemical reactions due to the release of nuclear energy from the nucleus.
<h3>Why is the energy released in a reaction?</h3>
Energy is released in a reaction due to the breaking of bonds are well as formation of bonds.
The quantity of energy released in reactions differs according to the reaction type involved.
When compared to chemical reactions, the energy released in nuclear reactions are very much higher because of the changes that occurs in the nucleus of the atoms involving nuclear energy.
The energy, E released in nuclear reactions is given by the formula below:

where m is the mass of the substance and c is the speed of light.
Therefore, the energy released in nuclear reactions are far larger than that released in chemical reactions.
Learn more about nuclear reactions at: brainly.com/question/984564
Answer:
mass and weight
Explanation:
because ur weight pulls you to the center of the earth