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Suppose a 0.025M aqueous solution of sulfuric acid (H2SO4) is prepared. Calculate the equilibrium molarity of SO4−2. You'll find

FromTheMoon [43]

Answer: The concentration of $SO_4^{2-}$ at equilibrium is 0.00608 M

Explanation:

As, sulfuric acid is a strong acid. So, its first dissociation will easily be done as the first dissociation constant is higher than the second dissociation constant.

In the second dissociation, the ions will remain in equilibrium.

We are given:

Concentration of sulfuric acid = 0.025 M

Equation for the first dissociation of sulfuric acid:

$H_2SO_4(aq.)\rightarrow H^+(aq.)+HSO_4^-(aq.)$

0.025 0.025 0.025

Equation for the second dissociation of sulfuric acid:

$HSO_4^-(aq.)\rightarrow H^+(aq.)+SO_4^{2-}(aq.)$

Initial: 0.025 0.025

At eqllm: 0.025-x 0.025+x x

The expression of second equilibrium constant equation follows:

$Ka_2=\frac{[H^+][SO_4^{2-}]}{[HSO_4^-]}$

We know that:

$Ka_2\text{ for }H_2SO_4=0.01$

Putting values in above equation, we get:

$0.01=\frac{(0.025+x)\times x}{(0.025-x)}\\\\x=-0.0411,0.00608$

Neglecting the negative value of 'x', because concentration cannot be negative.

So, equilibrium concentration of sulfate ion = x = 0.00608 M

Hence, the concentration of $SO_4^{2-}$ at equilibrium is 0.00608 M

4 0

3 years ago

Atoms of elements at the top of a group on the periodic table are smaller than the atoms of elements at the bottom of the group.

boyakko [2]

Answer:

Explanation:

As we move down the group atomic radii increased with increase of atomic number. The addition of electron in next level cause the atomic radii to increased. The hold of nucleus on valance shell become weaker because of shielding of electrons thus size of atom increased.

As the size of atom increases the ionization energy from top to bottom also decreases because it becomes easier to remove the electron because of less nuclear attraction and as more electrons are added the outer electrons becomes more shielded and away from nucleus.

On left side of periodic table atoms of metals are more reactive by loosing the electrons or we can say metals are more reactive by loosing the electrons so their reactivity increase down the group because of easily removal of electrons.

On right side of periodic table atoms of nonmetals are more reactive by gaining the electrons. As we move down the group nuclear attraction becomes smaller because of shielding thus electron are less attracted by nucleus and reactivity decreases.

7 0

3 years ago

Please help now!!! 20 braily points!!!

Zigmanuir [339]

Hydrogen atom and chlorine atom makes hydrogen chloride molecules.

It is the lowest point in the substance and possesses chemical elements. Atoms don't exist on their own; instead, they combine to create ions and molecules, which combine to create the substances that we can see, feel, and touch.

One or more atoms joined together by covalent (chemical) connections make up molecules. Atoms can be imagined as circles with a central nucleus (consisting of protons and neutrons) and one or more concentric circles surrounding it that represent the "shells" or "levels" in which the electrons surrounding the atom's nucleus are located as well as markings that distinguish the electron. every level

To know more about molecules visit : brainly.com/question/11405437

#SPJ1

4 0

1 year ago

Help please its science

Nookie1986 [14]

Answer: any answer choices

Explanation:

6 0

2 years ago

what is the molar mass of a gaseous flouride of sulfur containing 70.4% F and having a density of approximately 4.5g/L at 20 deg

zlopas [31]

Answer:

The molar mass is 180.2 g/mol

Explanation:

Step 1: Data given

% of F = 70.4 %

Density = 4.5 g/L

Temperature = 20 °C

Pressure = 1 atm

Step 2: Calculate the number of moles

PV = nRT

⇒ with P = the pressure = 1.00 atm

⇒ with V = the volume = Assume this is 1L

⇒ with n = the number of moles = TO BE DETERMINED

⇒ R = the gas constant = 0.08206 L*atm/K*mol

⇒ T = the temperature : 20°C = 293 Kelvin

1 atm*1L= n(0.08206 L-atm/mol-K)*(293 K)

n = 0.04159 moles

Step 3: Calculate molar mass

Molar mass = Mass / moles

4.5 grams / 0.04159 moles = 108.2 g/mol

Step 4: Calculate moles of F

Moles = Mass / molar mass

Moles F = 70.4 g / 19 g/mol

Moles F = 3.70 moles

Moles S = 29.6g / 32.07 g/mol

Moles S = 0.923 moles S

Step 5: Divide by the smallest amount of moles

F = 3.70 / 0.923 = 4

S = 0.923 / 0.923 = 1

The empirical formula is SF4

The molar mass of SF4 = 32.07 + 4*19 = 108.07 g/mol

This means the empirical formula is the same as the molecular formula SF4

The molar mass is 180.2 g/mol

4 0

3 years ago