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2 years ago

Write a mechanism for the formation of triphenylmethanol from the reaction of phenylmagnesium bromide and diethyl carbonate..

Chemistry

1 answer:

My name is Ann [436]2 years ago

5 0

The reaction proceeds through nucleophilic acyl substitution reaction.

Phenyl magnesium bromide substitutes one ethoxide ion in the nucleophilic acyl substitution reaction that drives the process forward. A subsequent equivalent of phenyl magnesium bromide produces triphenyl methanol through a nucleophilic addition reaction with the resultant keto group.

There are two ethoxy leaving groups in diethyl carbonate. Tertiary alcohol is created when diethyl carbonate combines with too much Grignard reagent. The Grignard reagent attacks the carbonyl carbon three times in the mechanism to produce the tertiary alcohol.

The mechanism is shown below:

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Which reaction most accurately represents the dissociation of nitrous acid (hno2) in water?

yanalaym [24]

When nitrous acid (HNO₂) dissociates in water (H₂O), the reaction that best captures this process is:

HNO₂ (aq.) + H₂O ↔ H₃O⁺ (aq.) + NO₂⁻ (aq.)

How does one know about HNO₂?

The chemical designation for nitrous acid is HNO₂, and it is a monoprotic acid. Three elements—hydrogen(H), oxygen(O), and nitrogen(N), all compose it.
It is highly fragile in nature and only occurs in solutions.
It is employed to convert amines into diazonium salts.

Is HNO₂ a basic or an acid?

Acidity is assigned to nitrous acid (HNO₂). Once dissolved in water, it gives out H+ ions. Acid is a chemical that produces H+ ions in a water-based solution or gives the protons to other molecules.

Thus, HNO₂ is acid because it causes a mixture of water to contain H+ ions. In a 10 mM concentration, it possesses a pH of 2.67.

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8 0

2 years ago

49.The 1H NMR spectrum of a compound with formula C7H14O gives a doublet at 9.2 ppm. Which of these structures is a possible one

4vir4ik [10]

Answer: The possible structure for this compound is 2,4-dimethyl-3-pentanone

Explanation:

It should be noted that, If the 1H NMR spectrum of a compound with formula C7H14O gives a doublet at 9.2 ppm. The possible structure for this compound is 2,4-dimethyl-3-pentanone

7 0

3 years ago

What is the periodic element symbol for gold?

Makovka662 [10]

Gold is Au on the periodic table

7 0

4 years ago

Consider the resonance structures of formate. the first lewis structure of formate has a central carbon atom. a hydrogen atom an

OleMash [197]

So,

Formate has a resonating double bond.

In molecular orbital theory, the resonating electrons are actually delocalized and are shared between the two oxygens. So the carbon-oxygen bonds can be described as 1.5-bonds (option B). I'm not sure if option C is correct, however, because the likelihood of both delocalized electrons being in the area of one oxygen atom is less than 50%.<span />

6 0

3 years ago

Hello everyone! I have a question about science;

kolezko [41]

C because 20 -10 is 10

4 0

3 years ago