The classification of the alcohols gives;
- Compound 1 - Primary alcohol
- Compound 2 - Tertiary alcohol
- Compound 3 - Secondary alcohol
- Compound 4 - Secondary alcohol
<h3>What are alcohols?</h3>
Organic compounds occurs in families. The family of compounds is called a homologous series. The homologous series always have a functional group. The functional group is the atom, group of atoms or bond that is responsible for the chemical reactivity of the members of a given homologous series.
Now we know that the alcohols are those organic compounds that contains the -OH group. The could be aliphatic or alicyclic compounds. We shall now proceed to name the kind of alcohols that each of the compounds shown are;
- Compound 1 - Primary alcohol
- Compound 2 - Tertiary alcohol
- Compound 3 - Secondary alcohol
- Compound 4 - Secondary alcohol
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Answer:
A reaction in which the entropy of the system decreases can be spontaneous only if it is exothermic.
Explanation:
The spontaneity of a reaction depends on the Gibbs free energy(ΔG).
- If ΔG < 0, the reaction is spontaneous.
- If ΔG > 0, the reaction is nonspontaneous.
ΔG is related to the enthalpy (ΔH) and the entropy (ΔS) through the following expression:
ΔG = ΔH - T.ΔS
where,
T is the absolute temperature (always positive)
Regarding the exchange of heat:
- If ΔH < 0, the reaction is exothermic.
- If ΔH > 0, the reaction is endothermic.
<em>Which statement is true? </em>
<em>A reaction in which the entropy of the system decreases can be spontaneous only if it is exothermic. </em>TRUE. If ΔS < 0, the term -T.ΔS > 0. ΔG can be negative only if ΔH is negative.
<em>A reaction in which the entropy of the system increases can be spontaneous only if it is endothermic.</em> FALSE. If ΔS > 0, the term -T.ΔS < 0. ΔG can be negative if ΔH is negative.
<em>A reaction in which the entropy of the system decreases can be spontaneous only if it is endothermic.</em> FALSE. If ΔS < 0, the term -T.ΔS > 0. ΔG cannot be negative if ΔH is positive.
<em>A reaction in which the entropy of the system increases can be spontaneous only if it is exothermic.</em> FALSE. If ΔS > 0, the term -T.ΔS < 0. ΔG can be negative even if ΔH is positive, as long as |T.ΔS| > |ΔH|.
What is the empirical formula for the molecular formula given? Molecular formula: C5H12O
Answer:
IHD = 0; no unsaturation in the formula
Explanation:
The IHD is also known as the degree of unsaturation formula. This formula is commonly used to get an idea of how many unsaturations a molecule has, and in this way, we can get an approach of the type of compound we are treating. For example, if this number is 1, it means that the compound has at least one unsaturation and it could be a double bond or just cyclical compound.
The IHD is calculated using the following expression:
IHD = (a + 1) - (b + x - c)/2 (1)
Where:
a: number of carbon
b: number of hydrogens
c: humber of nitrogens
x: number of halogens.
Now, we have the formula C₄H₉Cl, let's identify a, b, c and x:
a: 4 carbons; b = 9 hydrogens; C = none; X: 1 chlorine
Replacing in (1) we have:
IHD = (4+1) - (9+1)/2
IHD = 5 - (10/2)
<h2>
IHD = 0</h2>
So this number is 0, which means that the molecule does not have any kind of unsaturation (Non double bond, multi bond or cyclical).
Hope this helps