Direct electron transfer from a a singlet reduced species to a triplet oxidizing species is quantum-mechanically forbidden.
<h3><u>Transfer from singlet to triplet:</u></h3>
- Either an excited singlet state or an excited triplet state will occur when an electron in a molecule with a singlet ground state is stimulated (through radiation absorption) to a higher energy level.
- All electron spins in a molecule electronic state known as a singlet are coupled.
- In other words, the ground state electron and the stimulated electron's spin are still coupled (a pair of electrons in the same energy level must have opposite spins, per the Pauli exclusion principle).
- The excited electron and ground state electron are parallel in a triplet state because they are no longer coupled (same spin).
- It is less likely that a triplet state would arise when the molecule absorbs radiation since excitation to a triplet state necessitates an additional "forbidden" spin transfer.
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33 - 15 = 18
This element is P-33
Answer:
state ant two rights of women and children in relationships
The chemical formula for ammonium oxalate is C2H8N2O4
Answer:
Thus, the order of the reaction is 2.
The rate constant of the graph which is :- 2.00 M⁻¹s⁻¹
Explanation:
The kinetics of a reaction can be known graphically by plotting the concentration vs time experimental data on a sheet of graph.
The concentration vs time graph of zero order reactions is linear with negative slope.
The concentration vs time graph for a first order reactions is a exponential curve. For first order kinetics the graph between the natural logarithm of the concentration vs time comes out to be a straight graph with negative slope.
The concentration vs time graph for a second order reaction is a hyberbolic curve. Also, for second order kinetics the graph between the reciprocal of the concentration vs time comes out to be a straight graph with positive slope.
Considering the question,
A plot of 1/[NOBr] vs time give a straight line with a slope of 2.00 M⁻¹s⁻¹.
<u>Thus, the order of the reaction is 2.</u>
<u>Also, slope is the rate constant of the graph which is :- 2.00 M⁻¹s⁻¹</u>
