The ideal buffer's pH value is 4.74..
What is best buffer ?
The Best Buffer is a buffer that has equal amounts of the weak acid and its conjugate base. It responds well to the addition of acids and bases in order to fend off pH changes. A mixture of the weak base and its conjugate acid, or the weak acid and its conjugate base, is referred to as a buffer solution.
Here weak acid is acetic acid CH3COOH
The following equation can be used to determine a buffer's pH:
pH = pka + logconjugate baseweak acid
Now, the weak acid and its conjugate base are present in equal amounts in the optimal buffer.
Therefore,
Conjugate base = weak acid
This implies that,
pH = pka + log 1
pH = pka + 0
pH = pka
Now, pka can be written as -log ka
The value of ka is given as 1.8 * 10-5
Therefore,
pH = -log (1.8 * 10-5)
pH = 4.74
As a result, the ideal buffer has a pH of 4.74..
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