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xxMikexx [17]
2 years ago
15

D( )-Camphor is treated with 5-methoxytryptamine in the presence of sodium cyanoborohydride to generate a new molecule, as a sin

gle diastereomer, with molecular formula: C21H30N2O. Draw the starting materials, the imine intermediate, and the final product. (No mechanism is necessary). What is the rational for the reaction being diastereoselective (yielding a single diastereomer)
Chemistry
1 answer:
Svetach [21]2 years ago
4 0

The reducing agent can approach the carbonyl face of camphor by forming a one carbon bridge (known as an exo attack) or a two carbon bridge (termed endo).

The two resultant stereoisomers are known as isoborneol and borneol (from exo attack) (from endo attack). Gas chromatography (GC) analysis may be used to calculate the ratio of each isomeric alcohol in the mixture. Unfortunately, IR analysis does not permit this.

The stereochemistry of the reaction is regulated in stiff cyclic compounds like camphor and norcamphor by protecting one side of the carbonyl group from the reagent's assault. The hydrogen atom is added to the endo side, creating the exo alcohol isoborneol, while the methyl groups on the one-carbon bridge of camphor screen the approach of the hydride from the "top" or exo side of the two-carbon bridge. You will be asked to guess the main isomeric alcohol created by the norcamphor hydride reduction later in the lab report.

To view more about rational reaction, refer to:

brainly.com/question/20308523

#SPJ4

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I don’t even know that’s just weird
3 0
3 years ago
If 507 g FeCl2 were used up in the reaction FeCl2 + 2NaOH Fe(OH)2(s) + 2NaCl, how many grams of NaCl would be made?
Ket [755]
Number of moles of FeCl2 used = mass/ molar mass 
Number of moles = 507/126.751 = 4.
If one mole of Fe reacts with two moles of sodium 
Then 4 moles of Fe produces 8 moles of sodium.
Number of moles of sodium = mass/molar mass
Molar mass of sodium chloride = 23 +35.5 = 58.5 g/mol
Hence mass = 8 * 58.5 = 468 g. Hence Option A.

6 0
3 years ago
If you have 5.42 x 1024 aluminum atoms, approximately how many moles is that
sattari [20]

Answer:

<h2>9.00 moles</h2>

Explanation:

To find the number of moles in a substance given it's number of entities we use the formula

n =  \frac{N}{L} \\

where n is the number of moles

N is the number of entities

L is the Avogadro's constant which is

6.02 × 10²³ entities

From the question we have

n =  \frac{5.42 \times  {10}^{24} }{6.02 \times {10}^{23} }  \\  = 9.0033

We have the final answer as

<h3>9.00 moles</h3>

Hope this helps you

4 0
3 years ago
6. Describe the energy inputs and outputs for the campfire. Use the law of conservation of energy to construct a valid qualitati
Doss [256]

Answer:

Energy in the campfire originates from the potential chemical energy of the wood, before it is burnt to warm and give light around the campfire.

Explanation:

For a camp fire, the energy input is in the form of the potential chemical energy, stored up in the firewood used to fuel the flame.

The energy output is in the form of heat energy that the campfire radiates all around, light energy given off from the flame, and a little bit of sound energy, heard in the cracking of the firewood as they burn in the flame.

chemical energy ⇒ heat energy + light energy + sound energy

8 0
3 years ago
a- If an Lithium (atomic number 3) atom has a -2 charge, how many electrons does it have? b- Why do you do it this way? c- Is th
Darina [25.2K]

Answer:

5

Explanation:

A lithium atom with an atomic number of 3 and a charge of -2 will have a total number of electrons.

The atomic number is the number of protons in an atom. For a neutral atom that has not gained or lost electrons, the atomic number is the same as the number of electrons.

   neutral atom: atomic number of electrons

For neutral atom of lithium, we will have 3 electrons

Now, lithium with a charge of -2 has gained two more electrons to the original 3 this now makes it 5.

ii.

It is an anion because it is negatively charged.

Negatively charged particles are called anion.

6 0
2 years ago
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