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UNO [17]
1 year ago
10

1-Bromobutane reacts with water to form 1-butanol according to the following equation.

Chemistry
1 answer:
photoshop1234 [79]1 year ago
6 0

1-Bromobutane reacts with water to form 1-butanol according to the following equation overall rate law for this proposed mechanism is rate = k [C₄H₉Br]

The reaction intermediate in the chemical species that is formed in one elementary step and consumed in subsequent step and the slowest step in the reaction mechanism is rate determining step and the rate determining step limit the overall rate and therefore determines the rate law for the overall reaction

Here given reaction

C₄H₉Br(aq) + 2H₂O(l) → C₄H₉OH(aq) + H₃O⁺(aq) + Br⁻(aq)

And the following is a proposed mechanism for the reaction

C₄H₉Br(aq) → C₄H₉⁺(aq) + Br⁻(aq)     slow

C₄H₉⁺(aq) + H₂O(l) → C₄H₉OH₂⁺(aq)   fast

C₄H₉OH₂⁺(aq) + H₂O(l) → C₄H₉OH(aq) + H₃O⁺(aq)   fast

So in that 1st step is the rate determining step means slow step

So rate expressions take the general form: rate = k . [A]a . [B]b

So given equation rate expressions is k [C₄H₉Br]

Know more about rate expression

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What does reaction b tell you about the type of molecule h2co3 is?
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A 1.00 g sample of a metal X (that is known to form X ions in solution) was added to 127.9 mL of 0.5000 M sulfuric acid. After a
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<u>Answer:</u> The metal having molar mass equal to 26.95 g/mol is Aluminium

<u>Explanation:</u>

  • To calculate the number of moles for given molarity, we use the equation:

\text{Molarity of the solution}=\frac{\text{Moles of solute}}{\text{Volume of solution (in L)}}     .....(1)

Molarity of NaOH solution = 0.5000 M

Volume of solution = 0.03340 L

Putting values in equation 1, we get:

0.5000M=\frac{\text{Moles of NaOH}}{0.03340L}\\\\\text{Moles of NaOH}=(0.5000mol/L\times 0.03340L)=0.01670mol

  • The chemical equation for the reaction of NaOH and sulfuric acid follows:

2NaOH+H_2SO_4\rightarrow Na_2SO_4+H_2O

By Stoichiometry of the reaction:

2 moles of NaOH reacts with 1 mole of sulfuric acid

So, 0.01670 moles of NaOH will react with = \frac{1}{2}\times 0.01670=0.00835mol of sulfuric acid

Excess moles of sulfuric acid = 0.00835 moles

  • Calculating the moles of sulfuric acid by using equation 1, we get:

Molarity of sulfuric acid solution = 0.5000 M

Volume of solution = 127.9 mL = 0.1279 L    (Conversion factor:  1 L = 1000 mL)

Putting values in equation 1, we get:

0.5000M=\frac{\text{Moles of }H_2SO_4}{0.1279L}\\\\\text{Moles of }H_2SO_4=(0.5000mol/L\times 0.1279L)=0.06395mol

Number of moles of sulfuric acid reacted = 0.06395 - 0.00835 = 0.0556 moles

  • The chemical equation for the reaction of metal (forming M^{3+} ion) and sulfuric acid follows:

2X+3H_2SO_4\rightarrow X_2(SO_4)_3+3H_2

By Stoichiometry of the reaction:

3 moles of sulfuric acid reacts with 2 moles of metal

So, 0.0556 moles of sulfuric acid will react with = \frac{2}{3}\times 0.0556=0.0371mol of metal

  • To calculate the molar mass of metal for given number of moles, we use the equation:

\text{Number of moles}=\frac{\text{Given mass}}{\text{Molar mass}}

Mass of metal = 1.00 g

Moles of metal = 0.0371 moles

Putting values in above equation, we get:

0.0371mol=\frac{1.00g}{\text{Molar mass of metal}}\\\\\text{Molar mass of metal}=\frac{1.00g}{0.0371mol}=26.95g/mol

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A solution was found to have a 15.6 % transmittance at 500 nm, its wavelength of maximum absorption, using a cell with a path le
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<h3>What is the absorbance of the solution in a 1.00 cm cell at 500 nm?</h3>

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Generally, the equation for the Beer’s law is mathematically given as

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0.8069 = ε*c*(5.00 )

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then for when ε*c is constant

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In conclusion, the absorbance of the solution in a 1.00 cm cell at 500 nm is

A’ = 0.16138

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