C6H12O + 6OC2 + 6H2O + energy
Toichiometry time! Remember to look at the equation for your molar ratios in other problems.
31.75 g Cu | 1 mol Cu | 2 mol Ag | 107.9 g Ag 6851.65⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻ → ⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻ = 107.9 g Ag ∅ | 63.5 g Cu | 1 mol Cu | 1 mol Ag 63.5
There's also a shorter way to do this: Notice the molar ratio from Cu to Ag, which is 1:2. When you plug in 31.75 into your molar mass for Cu, it equals 1/2 mol. That also means that you have 1 mol Ag because of the ratio, qhich you can then plug into your molar mass, getting 107.9 as well.
<h3><em><u>solution</u></em><em><u>:</u></em></h3>
<em><u>The initial entropy is obtained from the initial pressure and temperature with data from A-6 using interpolation:</u></em>
<em><u>s</u></em><em><u>=</u></em><em><u> </u></em><em><u>8</u></em><em><u>.</u></em><em><u>26</u></em><em><u>5</u></em><em><u>2</u></em><em><u> </u></em><em><u>kJ</u></em><em><u>/</u></em><em><u>kgK</u></em>
<em><u>The final temperature is determined from the entropy and the final pressure with data from A-6 using interpolation:</u></em>
<em><u>T₂ = T₁+</u></em><em><u> </u></em><em><u>T₂ - </u></em><em><u>T₁</u></em><em><u>/</u></em><em><u> </u></em><em><u>8</u></em><em><u>₂</u></em><em><u> </u></em><em><u>-</u></em><em><u> </u></em><em><u>8</u></em><em><u>₁</u></em><em><u> </u></em><em><u>(</u></em><em><u> </u></em><em><u>s</u></em><em><u> </u></em><em><u>-</u></em><em><u> </u></em><em><u>s</u></em><em><u>₁</u></em><em><u>)</u></em>
<em><u>= </u></em><em><u>(</u></em><em><u>400 +</u></em><em><u> </u></em><em><u>500 - 400</u></em><em><u>/</u></em><em><u>8.3271</u></em><em><u> </u></em><em><u>-</u></em><em><u> </u></em><em><u>8.0347</u></em><em><u> </u></em><em><u>(8.2652 - 8</u></em><em><u>)</u></em><em><u>)</u></em>
<em><u>= 478.83°C</u></em>
<em><u>The final enthalpy is determined in the same way:</u></em>
<em><u>h₂= h₁</u></em><em><u> </u></em><em><u>+</u></em><em><u> </u></em><em><u>h₂</u></em><em><u> </u></em><em><u>-</u></em><em><u> </u></em><em><u>h₁</u></em><em><u>/</u></em><em><u>s</u></em><em><u>₂</u></em><em><u> </u></em><em><u>-</u></em><em><u> </u></em><em><u>s</u></em><em><u>₁</u></em><em><u> </u></em><em><u>( s - s₁)</u></em>
<em><u>= (</u></em><em><u> </u></em><em><u>3275.5</u></em><em><u>+</u></em><em><u> </u></em><em><u>3486.6 </u></em><em><u>-</u></em><em><u> </u></em><em><u>3275.5</u></em><em><u>/</u></em><em><u> </u></em><em><u>8.3271</u></em><em><u> </u></em><em><u>-</u></em><em><u> </u></em><em><u>8.0347</u></em><em><u>)</u></em><em><u> </u></em><em><u>(8.265</u></em><em><u>)</u></em>
<em><u>=</u></em><em><u> </u></em><em><u>3441.91 </u></em><em><u>kJ</u></em><em><u>/</u></em><em><u>kg</u></em>
Answer:- C. Hafnium.
Solution:- Mass of the sample is 46.0 g and it's volume is
.
From mass and volume, we can calculate it's density using the formula:



On the basis of the density, this substance could either be mercury or hafnium. Since the substance is a solid at room temperature where as mercury is liquid. So, it can't be mercury.
The right choice is C) Hafnium.