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The land breeze arrow is correct
The rest are incorrect.
Warm air should 'rise' by the land
This air then moves towards the sea and cools down
The cool air would then sink
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The balanced equation for the above reaction is as follows;
2HCl + K₂SO₃ ---> 2KCl + H₂O + SO₂
stoichiometry of HCl to SO₂ is 2:1
number of moles of HCl reacted - 15.0 g / 36.5 g/mol = 0.411 mol
according to molar ratio
number of SO₂ moles formed - 0.411 mol /2 = 0.206 mol
since we know the number of moles we can find volume using ideal gas law equation
PV = nRT
where
P - pressure - 1.35 atm x 101 325 Pa/atm = 136 789 Pa
V - volume
n - number of moles - 0.206 mol
R - universal gas constant - 8.314 Jmol⁻¹K⁻¹
T - temperature - 325 K
substituting values in the equation
136 789 Pa x V = 0.206 mol x 8.314 Jmol⁻¹K⁻¹ x 325 K
V = 4.07 L
volume of SO₂ formed is 4.07 L
Answer:- 0.273 kg
Solution:- A double replacement reaction takes place. The balanced equation is:

We have 0.29 L of 22% m/v aluminum nitrate solution. m/s stands for mass by volume. 22% m/v aluminium nitrate solution means 22 g of it are present in 100 mL solution. With this information, we can calculate the grams of aluminum nitrate present in 0.29 L.

= 63.8 g aluminum nitrate
From balanced equation, there is 1:3 mol ratio between aluminum nitrate and sodium chlorate. We will convert grams of aluminum nitrate to moles and then on multiplying it by mol ratio we get the moles of sodium chlorate that could further be converted to grams.
We need molar masses for the calculations, Molar mass of sodium chlorate is 106.44 gram per mole and molar mass of aluminum nitrate is 212.99 gram per mole.

= 
sodium chlorate solution is 35% m/m. This means 35 g of sodium chlorate are present in 100 g solution. From here, we can calculate the mass of the solution that will contain 95.7 g of sodium chlorate and then the grams are converted to kg.

= 0.273 kg
So, 0.273 kg of 35% m/m sodium chlorate solution are required.
<span>
Phenobarbital is derivative of
Barbituric Acid and Barbituric Acid is derivative of
Urea. (structures shown in Fig below)
Urea has H</span>₂N- group attached to Carbonyl Group (C=O), and such class of comounds conataining H₂N-C=O bond are called as Amides.
Result: So, <span>Phenobarbital belongs to
Amides.</span>