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DENIUS [597]
1 year ago
13

Nh4cl is sometimes preferred instead of hcl or h2so4 for "acid" work-up after grignard reactions, particularly when the expected

and desired product is a tertiary alcohol. Why?
Chemistry
1 answer:
Free_Kalibri [48]1 year ago
6 0

Nh4cl is sometimes preferred instead of hcl or h2so4 for "acid" work-up after grignard reactions, particularly when the expected and desired product is a tertiary alcohol because NH4+ is a much milder acid than HCl or H2SO4, which achieve the protonation of

the oxyanion to yield the alcohol while minimizing the risk of dehydration.

Ammonium chloride (NH4Cl) is the used as reagent that quenches the magnesium alkoxide product of the Grignard addition.

It is a proton source without being acidic as in acidic medium the protonation of the tertiary alcohol product and elimination to the alkene.

In the presence of HCl or any other strong acid protonation proceed and form alkene but not with ammonium chloride.

Thus from above we concluded that Nh4cl is preferred instead of hcl or h2so4 for "acid" work-up after grignard reactions.

learn more about grignard reagent:

brainly.com/question/15876201

#SPJ4

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From 1962 until 1981 pennies were made from 95% copper and 5% zinc and had a mass of 3.1 g. Starting in 1982, pennies have been
Sloan [31]

Answer:

2.7724 g

Explanation:

Mass of pre- 1892 pennies = 3.1 g

Abundance = 45.4 %

Mass of post 1892 pennies = 2.5 g

Abundance = 100 - 45.4 = 54.6 %

The average mass is given as = ( 3.1 g   *  45.4 / 100)  +  (2.5g  *  54.6 / 100)

Average Mass = 3.1 * 0.454   +   2.5  *  0.546

Average Mass = 1.4074  + 1.365 = 2.7724 g

8 0
3 years ago
Water is poured into a conical container at the rate of 10 cm3/sec. The cone points directly down, and it has a height of 20 cm
8090 [49]

Answer:

\frac{dh}{dt}_{h=2cm} =\frac{40}{9\pi}\frac{cm}{2}

Explanation:

Hello,

The suitable differential equation for this case is:

\frac{dV}{dt}=10\frac{cm^3}{s}

As we're looking for the change in height with respect to the time, we need a relationship to achieve such as:

\frac{dh}{dt} = ?*\frac{dV}{dt}

Of course, ?=\frac{dh}{dV}.

Now, since the volume of a cone is V=\pi r^2h/3 and the ratio r/h=15/20=3/4 or r=3/4h, the volume becomes:

V=\pi (\frac{3}{4} h)^2h/3= \frac{3}{16}\pi h^3

We proceed to its differentiation:

\frac{dV}{dh} =\frac{9}{16} \pi h^2\\\frac{dh}{dV} =\frac{16}{9 \pi h^2}

Then, we compute \frac{dh}{dt}

\frac{dh}{dt} = \frac{16}{9 \pi h^2}*\frac{dV}{dt}\\\frac{dh}{dt} = \frac{16}{9\pi h^2}*10\frac{cm^3}{s} =\frac{160}{9 \pi h^2}

Finally, at h=2:

\frac{dh}{dt}_{h=2cm} =\frac{160}{9\pi 2^2}\\\frac{dh}{dt}_{h=2cm} =\frac{40}{9\pi}\frac{cm}{s}

Best regards.

4 0
3 years ago
If 16.5g of c6h14o2 are reacted vwith .499 mol of o2. How many moles of co2 should be produced
Fed [463]

Answer:

moles of carbon dioxide produced are 410.9 mol.

Explanation:

Given data:

Mass of C₆H₁₄O₂ = 16.5 g

Moles of O₂ = 499 mol

Moles of CO₂ = ?

First of all we will write the balance chemical equation.

2C₆H₁₄O₂  +  17O₂  →   14CO₂  +  12H₂O

moles of C₆H₁₄O₂  = mass × molar mass

moles of C₆H₁₄O₂ =  16.5 g × 118 g/mol

moles of C₆H₁₄O₂ = 1947 mol

Now we compare the moles of CO₂ with moles of O₂ and C₆H₁₄O₂ from balance chemical equation.

                 O₂      :     CO₂

                 17       :      14

                499     :      14/17× 499 = 410.9 moles

          C₆H₁₄O₂   :   CO₂

                    2    :      14

                 1947 :     14/2× 1947 =  13629 moles

Oxygen will be limiting reactant so moles of carbon dioxide produced are 410.9 mol.

5 0
4 years ago
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As a forensic expert, Jane needs to handle many biological evidence samples simultaneously. What is the basic precaution that sh
madreJ [45]

Answer:

B.  use a new pair of gloves for each piece of evidence

Explanation:

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Wearing of gloves will also <em>prevent Jane's DNA from being implanted into the sample</em>, and it will keep her safe from contracting blood-borne pathogens like those in the saliva, blood or semen.

7 0
3 years ago
2+2=4 and the. You add 7
Marat540 [252]
Do you mean 4+7 if yes it’s 11
8 0
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