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DENIUS [597]
1 year ago
13

Nh4cl is sometimes preferred instead of hcl or h2so4 for "acid" work-up after grignard reactions, particularly when the expected

and desired product is a tertiary alcohol. Why?
Chemistry
1 answer:
Free_Kalibri [48]1 year ago
6 0

Nh4cl is sometimes preferred instead of hcl or h2so4 for "acid" work-up after grignard reactions, particularly when the expected and desired product is a tertiary alcohol because NH4+ is a much milder acid than HCl or H2SO4, which achieve the protonation of

the oxyanion to yield the alcohol while minimizing the risk of dehydration.

Ammonium chloride (NH4Cl) is the used as reagent that quenches the magnesium alkoxide product of the Grignard addition.

It is a proton source without being acidic as in acidic medium the protonation of the tertiary alcohol product and elimination to the alkene.

In the presence of HCl or any other strong acid protonation proceed and form alkene but not with ammonium chloride.

Thus from above we concluded that Nh4cl is preferred instead of hcl or h2so4 for "acid" work-up after grignard reactions.

learn more about grignard reagent:

brainly.com/question/15876201

#SPJ4

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The equilibrium constant, Kc, is calculated using molar concentrations. For gaseous reactions another form of the equilibrium co
Anarel [89]

Answer:

Kp = 1.41 x 10⁻⁶

Explanation:

We have the chemical equation:

2 A(g) + 3 B(g)⇌ C(g)

In which A and B are the reactants and C is the product. We calculate first the change in the number of moles of gas (Δn or dn):

dn= (sum moles products - sum moles reactants)

   = (moles C - (moles A + moles B))

   = (1 - (2+3))

   = 1 - 5

   = -4

We have also the following data:

Kc = 63.2

T= 81∘C + 273 = 354 K

R = 0.082 L.atm/K.mol (it is a constant)

Thus, we introduce the data in the mathematical expression for the relation between Kp and Kc:

Kc = (RT)^{dn}= (0.082 L.atm/K.mol x 354 K)⁻⁴ = 1.41 x 10⁻⁶

3 0
3 years ago
AIDS is one disease caused by a virus infection. The virus attacks immune system cells known as T cells.
VLD [36.1K]

Answer:

yes,its true

Explanation:

I just want to say first off

the immune cell known as T cell also known as white blood cells

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CD4 cells are the basic T cells and HIV virus which is AIDS will start to "Eat itself inside" Ofc not they will use protein spikes to form their way in

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They are able to bypass CD4 cells is because its a basic cellular receptor for T cells making them really deadly

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7 0
3 years ago
What mass of barium sulfate (233 g/mol) is produced when 125 mL of a 0.150 M solution of barium chloride is mixed with 125 mL of
Rzqust [24]

Answer:

4.37 g of barium sulphate

Explanation:

The reaction equation is;

3BaCl2(aq) + Fe2(SO4)3(aq) ---->3 BaSO4(s) + 2FeCl3(aq)

From the question, the number of moles of both barium chloride and FeSO4 = 125/1000 L × 0.150 M = 0.01875 moles

To find the limiting reactant;

3 moles of barium chloride yields 3 moles of barium sulphate

0.01875 moles of barium chloride yields 3 × 0.01875 moles/3 = 0.01875 moles of barium sulphate

1 mole of iron III sulphate yields 3 moles of barium sulphate

0.01875 molesof iron III sulphate yields 0.01875 moles ×3/1 = 0.05625 moles of barium sulphate

Hence,barium chloride is the limiting reactant

Amount of barium sulphate produced = 0.01875 moles × 233 g/mol = 4.37 g of barium sulphate

4 0
2 years ago
A volume of 90.0 mL of aqueous potassium hydroxide (KOH) was titrated against a standard solution of sulfuric acid (H2SO4). What
Gemiola [76]

Answer:

The answer to your question:  0.7 M

Explanation:

Data

V of KOH = 90 ml

[KOH] = ?

V H2SO4 = 21.2 ml

[H2SO4] = 1.5 M

                       2KOH(aq)  +  H₂SO₄(aq)   →   K₂SO₄(aq)  +  2H₂O(l)

Molarity = moles / volume

moles of H₂SO₄ = (1.5) (21.2)

                           = 31.8

                    2 moles of KOH --------------  1 mol of H₂SO₄

                   x                           --------------  31.8 mol of H₂SO₄

                    x = (31.8)(2) / 1

                    x = 63.8 moles of KOH

Molarity = 63.8 / 90

             = 0.7 M

7 0
3 years ago
What happens in a condensation reaction?
Agata [3.3K]

A) Head to tail joining of monomers. :) (confirmed correct answer, I took the test)

8 0
3 years ago
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