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enyata [817]
3 years ago
8

A 55.0 mL aliquot of a 1.50 M solution is diluted to a total volume of 278 mL. A 139 mL portion of that solution is diluted by a

dding 155 mL of water. What is the final concentration? Assume the volumes are additive. concentration:
Chemistry
2 answers:
yaroslaw [1]3 years ago
6 0

Answer:

The final concentration is 0.140 M

Explanation:

  • We have to calculate the moles of the first aliquot:

n₁=M₁.V₁ (First equation)

n₁=1.50 M

V₁=55 mL

  • Now we have to calculate the concentration of the second solution knowing that the moles of the first aliquot (278 mL) and the moles of the second solution are the same:

M₂=n₂/V₂ (Second Equation)

V₂=278 mL

n₁=n₂

  • If we substitute the first equation into the second one, we obtain the following:

M₂=M₁.(V₁/V₂) (Third Equation)

  • The second aliquot (139 mL) has the same concentration as the second solution, so we need to calculate the moles:

n₃=M₃.V₃ (Forth Equation)

V₃=139 mL

M₃=M₂

  • If we substitute the third equation into the forth one, we obtain:

n₃=M₁.(V₁/V₂).V₃ (Forth Equation)

  • Now we have to calculate the concentration of the final solution, knowing that the moles of second aliquot are the same as the moles of the final solution:

M₄=n₄/V₄ (Fifth Equation)

n₄=n₃

  • When we substitute the Forth Equation into the fifth one, we obtain:

M₄=M₁.(V₁/V₂).(V₃/V₄) (Sixth equation)

  • Now we have to remember that the volume of the final solution is:

V₄=V₃+155 mL (Seventh Equation)

  • Now we substitute the seventh equation into the sixth one and we obtain:

M₄=M₁.(V₁/V₂).(V₃/(V₃+155 mL))

M₄=1.50 M . (55mL / 278 mL) . ((139mL)/(139mL+155mL))

M₄=1.50 M . (55mL / 278 mL) . (139mL/294mL)

M₄=0.140 M

balu736 [363]3 years ago
4 0

Answer:

0.14 M

Explanation:

To determinate the concentration of a new solution, we can use the equation below:

C1xV1 = C2xV2

Where C is the concentration, and V the volume, 1 represents the initial solution, and 2 the final one. So, first, the initial concentration is 1.50 M, the initial volume is 55.0 mL and the final volume is 278 mL

1.50x55.0 = C2x278

C2 = 0.30 M

The portion of 139 mL will be the same concentration because it wasn't diluted or evaporated. The final volume will be the volume of the initial solution plus the volume of water added, V2 = 139 + 155 = 294 mL

Then,

0.30x139 = C2x294

C2 = 0.14 M

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Answer:

d, 40 dm3.

Explanation:

According to Avogadro's law, the mole ratio of chemicals in a reaction is equal to the ratio of volumes of chemicals reacted (for gas).

From the equation, the mole ratio of N2 : H2 : NH3 = 1 : 3 : 2, meaning 1 mole of N2 reacts completely with 3 moles of H2 to give 2 moles of NH3, the ratio of volume required is also equal to 1 : 3 : 2.

Considering both N2 and H2 have 30dm3 of volume, but 1 mole of N2 reacts completely with 3 moles of H2, so we can see H2 is limiting while N2 is in excess. Using the ratio, we can deduce that 10dm3 equals to 1 in ratio (because 3 moles ratio = 30dm3).

With that being said, all H2 has reacted, meaning there's no volume of H2 left.  2 moles of NH3 is produced, meaning the volume of NH3 produced = 10 x 2 = 20 dm3. (using the ratio again)

1 mole of N2 has reacted, meaning from the  30dm3, only 10 dm3 has reacted. This also indicate that 20 dm3 of N2 has not been reacted.

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