ΔHrxn = ΣδΗ(bond breaking) - ΣδΗ(bond making)
Bond enthalpies,
N ≡ N ⇒ 945 kJ mol⁻¹
N - Cl ⇒ 192 kJ mol⁻¹
Cl - Cl⇒ 242 kJ mol⁻¹
According to the balanced equation,
ΣδΗ(bond breaking) = N ≡ N x 1 + Cl - Cl x 3
= 945 + 3(242)
= 1671 kJ mol⁻¹
ΣδΗ(bond making) = N - Cl x 3 x 2
= 192 x 6
= 1152 kJ mol⁻¹
δHrxn = ΣδΗ(bond breaking) - ΣδΗ(bond making)
= 1671 kJ mol⁻¹ - 1152 kJ mol⁻¹
= 519 kJ mol⁻¹
Answer:
solid
Explanation:
in the solid state the material will has a fixed shape and volume whatever the container that contains it
where in liquid the shape will be different depending on the container
and in gas state the shape and volume are not definite
Sucrose is insoluble in dichloromethane because dichloromethane is not a polar solvent.
Sucrose is soluble in water because the molecules of sucrose has the ability to react with the molecules of water and thereby forming hydrogen bond which enhance the dispersion of sucrose in the water.
Sugar can not react in a similar way with dichloromethane because they do not possess chemical species that can react together to form bonds. Thus, sugar is a polar substance which can not dissolve in a non-polar solvent.
