I think its because its more accurate because it shows you the numbers rather than you reading the approximate temperature on a liquid thermometer
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The empirical formula of the following compounds 0.903 g of phosphorus combined with 6.99 g of bromine.
<h3>What is empirical formula?</h3>
The simplest whole number ratio of atoms in a compound is the empirical formula of a chemical compound in chemistry. Sulfur monoxide's empirical formula, SO, and disulfur dioxide's empirical formula, S2O2, are two straightforward examples of this idea. As a result, both the sulfur and oxygen compounds sulfur monoxide and disulfur dioxide have the same empirical formula.
<h3>
How to find the empirical formula?</h3>
Convert the given masses of phosphorus and bromine into moles by multiplying the reciprocal of their molar masses. The molar masses of phosphorus and bromine are 30.97 and 79.90 g/mol, respectively.
Moles phosphorus = 0.903 g phosphorus
= 0.0293 mol
Moles bromine 6.99 g bromine
=0.0875 mol
The preliminary formula for compound is P0.0293Bro.0875. Divide all the subscripts by the subscript with the smallest value which is 0.0293. The empirical formula is P1.00Br2.99 ≈ P₁Br3 or PBr3
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a) First, to get ΔG°rxn we have to use this formula when:
ΔG° = - RT ㏑ K
when ΔG° is Gibbs free energy
and R is the constant = 8.314 J/mol K
and T is the temperature in Kelvin = 25 °C+ 273 = 298 K
and when K = 4.4 x 10^-2
so, by substitution:
ΔG°= - 8.314 * 298 *㏑(4.4 x 10^-2)
= -7739 J = -7.7 KJ
b) then, to get E° cell for a redox reaction we have to use this formula:
ΔE° Cell = (RT / nF) ㏑K
when R is a constant = 8.314 J/molK
and T is the temperature in Kelvin = 25°C + 273 = 298 K
and n = no.of moles of e- from the balanced redox reaction= 3
and F is Faraday constant = 96485 C/mol
and K = 4.4 x 10^-2
so, by substitution:
∴ ΔE° cell = (8.314 * 298 / 3* 96485) *㏑(4.4 x 10^-2)
= - 2.7 x 10^-2 V
Answer : The number of moles in 369 grams of calcium hydroxide is, 4.98 moles
Explanation : Given,
Mass of calcium hydroxide = 369 g
Molar mass of calcium hydroxide = 74.093 g/mole
Formula used :

Now put all the given values in this formula, we get the moles of calcium hydroxide.

Therefore, the number of moles in 369 grams of calcium hydroxide is, 4.98 moles