Answer:
16.06 L was the initial volume of the balloon.
Explanation:
Initial moles of freon in ballon = 
Initial volume of freon gas in ballon = 
Moles of freon gas added in the balloon = n = 3.50 mole
Final moles of freon in ballon = 
Final volume of freon gas in ballon = 
Using Avogadro's law:
( at constant pressure and temperature)

16.06 L was the initial volume of the balloon.
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Or do you want it in a reaction problem?
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Ba! It is a metal and wants to lose 2 electrons ASAP
Volcanic eruptions are caused by earth's internal heat sources.
All the other choices are atmospheric or external earth.