Balanced equation: 2Na(s) + Cl₂(g) ---> 2NaCl(s)
when we have STP conditions, we can use this conversion: 1 mol = 22.4 L
first, we have to convert grams to molecules using the molar mass, and then use mole to mole ratio from the balanced equation.
molar mass of Na= 23.0 g/mol
ratio: 2 mol Na= 1 mol Cl₂ (based on coefficients of balanced equation)
calculations:
Answer:- It is choice D. 
Explanations:- In general, a neutralization reaction is the reaction of an acid with base to form salt and water.
in first reaction the reaction is taking place between ammonia(a base) and hydrochloric acid(an acid) to form their salt(ammonium chloride). So, it is an acid-base neutralization reaction.
In second reaction, sodium hydroxide(a base) is reacting with acetic acid(an acid) to form their salt(sodium acetate) and water. So, it is an acid-base neutralization reaction.
In third reaction, Nitric acid is reacting with calcium hydroxide(a base) to form a salt(calcium nitrate) and water. So, it is an acid-base neutralization reaction.
In fourth reaction, sulfuruc acid is reacting a sodium chloride(a salt) to give a double replacement reaction. It is not an acid-base neutralization reaction as it's not taking place between an acid and base.
So, the correct choice is D. 
Covalent Bond.
To be specific, it is polar covalent bond. :)