A colored line, as long as it is one single piece, not broken
In the presence of heat, copper (II) hydroxide decomposes in to copper (II) oxide.
Cu(OH)₂ (s) ----> CuO (s) + H₂O (l)
upon decomposition, water is removed from Cu(OH)₂
the amount of Cu(OH)₂ decomposed - 3.67 g
number of moles of Cu(OH)₂ - 3.67 g / 97.5 g/mol = 0.038 mol
stoichiometry of Cu(OH)₂ to CuO is 1:1
therefore number of CuO moles formed are - 0.038 mol
CuO reacts with sulfuric acid to form CuSO₄
CuO + H₂SO₄ ---> CuSO₄ + H₂O
stoichiometry of CuO to H₂SO₄ is 1:1
therefore number of H₂SO₄ moles that should react is 0.038 mol
the molarity of H₂SO₄ is 3M
this means that in 1000 ml - 3 mol of H₂SO₄ present
so if 3 mol are present in 1000 ml
then volume for 0.038 mol = 1000/3 * 0.038
= 12.67 ml
Answer:
![\mathbf{s =\sqrt [3]{\dfrac{K_{sp}}{4}}}](https://tex.z-dn.net/?f=%5Cmathbf%7Bs%20%3D%5Csqrt%20%5B3%5D%7B%5Cdfrac%7BK_%7Bsp%7D%7D%7B4%7D%7D%7D)
Less than the concentration of Pb2+(aq) in the solution in part ( a )
Explanation:
From the question:
A)
We assume that s to be the solubility of PbI₂.
The equation of the reaction is given as :
PbI₂(s) ⇌ Pb²⁺(aq) + 2I⁻(aq); Ksp = 7 × 10⁻⁹
[Pb²⁺] = s
Then [I⁻] = 2s
![K_{sp} =\text{[Pb$^{2+}$][I$^{-}$]}^{2} = s\times (2s)^{2} = 4s^{3}\\s^{3} = \dfrac{K_{sp}}{4}\\\\s =\mathbf{ \sqrt [3]{\dfrac{K_{sp}}{4}}}\\\\\text{The mathematical expressionthat can be used to determine the value of }\mathbf{s =\sqrt [3]{\dfrac{K_{sp}}{4}}}](https://tex.z-dn.net/?f=K_%7Bsp%7D%20%3D%5Ctext%7B%5BPb%24%5E%7B2%2B%7D%24%5D%5BI%24%5E%7B-%7D%24%5D%7D%5E%7B2%7D%20%3D%20s%5Ctimes%20%282s%29%5E%7B2%7D%20%3D%20%204s%5E%7B3%7D%5C%5Cs%5E%7B3%7D%20%3D%20%5Cdfrac%7BK_%7Bsp%7D%7D%7B4%7D%5C%5C%5C%5Cs%20%3D%5Cmathbf%7B%20%5Csqrt%20%5B3%5D%7B%5Cdfrac%7BK_%7Bsp%7D%7D%7B4%7D%7D%7D%5C%5C%5C%5C%5Ctext%7BThe%20mathematical%20expressionthat%20can%20be%20used%20to%20determine%20the%20value%20of%20%20%7D%5Cmathbf%7Bs%20%3D%5Csqrt%20%5B3%5D%7B%5Cdfrac%7BK_%7Bsp%7D%7D%7B4%7D%7D%7D)
B)
The Concentration of Pb²⁺ in water is calculated as :
![\mathbf{s =\sqrt [3]{\dfrac{K_{sp}}{4}}}](https://tex.z-dn.net/?f=%5Cmathbf%7Bs%20%3D%5Csqrt%20%5B3%5D%7B%5Cdfrac%7BK_%7Bsp%7D%7D%7B4%7D%7D%7D)
![\mathbf{s =\sqrt [3]{\dfrac{7*10^{-9}}{4}}}](https://tex.z-dn.net/?f=%5Cmathbf%7Bs%20%3D%5Csqrt%20%5B3%5D%7B%5Cdfrac%7B7%2A10%5E%7B-9%7D%7D%7B4%7D%7D%7D)
![\mathbf{s} =\sqrt[3]{1.75*10^{-9}}](https://tex.z-dn.net/?f=%5Cmathbf%7Bs%7D%20%3D%5Csqrt%5B3%5D%7B1.75%2A10%5E%7B-9%7D%7D)

The Concentration of Pb²⁺ in 1.0 mol·L⁻¹ NaI




The equilibrium constant:
![K_{sp} =[Pb^{2+}}][I^-]^2 \\ \\ K_{sp} = s*(1.0*2s)^2 =7*1.0^{-9} \\ \\ s = 7*10^{-9} \ \ m/L](https://tex.z-dn.net/?f=K_%7Bsp%7D%20%3D%5BPb%5E%7B2%2B%7D%7D%5D%5BI%5E-%5D%5E2%20%5C%5C%20%5C%5C%20K_%7Bsp%7D%20%3D%20s%2A%281.0%2A2s%29%5E2%20%3D7%2A1.0%5E%7B-9%7D%20%5C%5C%20%5C%5C%20s%20%3D%207%2A10%5E%7B-9%7D%20%5C%20%5C%20%20m%2FL)
It is now clear that maximum possible concentration of Pb²⁺ in the solution is less than that in the solution in part (A). This happens due to the common ion effect. The added iodide ion forces the position of equilibrium to shift to the left, reducing the concentration of Pb²⁺.
A0 = 1
a1 = 2
a2 = 1
a3 = 2
This can be solved by guessing and checking and making sure that all atoms on the left side are accounted for on the right side. Both sides must have the same amount of atoms or the balancing is not correct.
Answer:
D)
Explanation:
seems like the most logical option out of all listed.