The substance is an element off of the periodic table.
If you count the number of electrons (small dots), you have the atomic number. In this case you have 11 so this atom is a sodium atom. Sodium has 1 valence electron (electron on the outer shell) and chlorine has 7. This means that if sodium gave one electron away and chlorine would obtain one electron, they would both have the (ideal) noble gas conformation (full outer shell).
D. this is the correct answer because the question is showing a comparison of sizes rather than the actual sizes which eliminates B. A and C have no relevance.
To calculate for the final temperature, we need to remember that the heat rejected should be equal to the absorbed by the other system. We calculate as follows:
Q1 = Q2
(mCΔT)1 = (mCΔT)2
We can cancel m assuming the two systems are equal in mass. Also, we cancel C since they are the same system. This leaves us,
(ΔT)1 = (ΔT)2
(T - 80) = (0 - T)
T = 40°C