The bigger the atomic radius the easier it is to oxidise the atom. Remember that an atom is oxidized by the loss of an electron.
Explanation:
The bigger the atomic radius the further away the valence electron are from the attractive force of the atomic nucleus. This means that the energy required to remove an electron from the valence shell is easier compared to an atom with a smaller atomic radius. This is because you need to overcome the attractive force of the nucleus on the electron for you to oxidize the atom.
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For more on oxidation energy check out;
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Use photomath. I would really recommend it! Hope this helps!
Explanation:
Lithium diisopropylamide (LDA) is used in many organic synthesis and is a strong base. It is prepared by the acid base reaction of N,N-diisopropylamine ( [(CH₃)₂CH]₂NH ) and butyllithium ( Li⁺⁻CH₂CH₂CH₂CH₃ ).
The equation is show below as:
[(CH₃)₂CH]₂NH + Li⁺⁻CH₂CH₂CH₂CH₃ ⇒ [(CH₃)₂CH]₂N⁻Li⁺ + CH₃CH₂CH₂CH₃
N,N-diisopropylamine ( [(CH₃)₂CH]₂NH ) is a weaker acid and hence, LDA ( [(CH₃)₂CH]₂N⁻Li⁺ ) is stronger base. (Weaker acid has stronger conjugate base)
Butyllithium ( Li⁺⁻CH₂CH₂CH₂CH₃ ) is a very strong base and hence, butane ( CH₃CH₂CH₂CH₃ ) is a very weak acid. (Strong base has weaker conjugate acid)
