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PIT_PIT [208]
3 years ago
12

The [α] of pure quinine, an antimalarial drug, is −165. If a solution contains 86% quinine and 14% of its enantiomer (ee = 72%),

what is [α] for the solution?
Chemistry
1 answer:
ratelena [41]3 years ago
4 0

Answer : The [α] for the solution is, -118.8

Explanation :

Enantiomeric excess : It is defined as the difference between the percentage major enantiomer and the percentage minor enantiomer.

Mathematically,

\%\text{ Enantiomer excess}=\%\text{ Major enantiomer}-\%\text{ Minor enantiomer}

Given:

% major enantiomer = 86 %

% minor enantiomer = 14 %

Putting values in above equation, we get:

\%\text{ Enantiomer excess}=86\%-14\%=72\%

\text{ Enantiomer excess}=\frac{72}{100}=0.72

Now we have to calculate the [α] for the solution.

[\alpha]=\text{Enantiomer excess}\times [\alpha]_{Pure}

[\alpha]=0.72\times -165

[\alpha]=-118.8

Thus, the [α] for the solution is, -118.8

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